Publications
Updated February 2008
To request publications not posted here, please contact Prof Garcia-Garibay at
mgg@chem.ucla.edu
(133) Chin, K. K.; Trevithick-Sutton, C.C.; McCallum, J.; Jockusch, S.; Turro,
N.J.; Scaiano, J.C.; Foote, C.S.; Garcia-Garibay, M.A. "Quantitative Determination
of Singlet Oxygen Generated by Excited State Aromatic Amino Acids, Proteins, and
Immunoglobulins" J. Am. Chem. Soc. 2008, 130, Manuscript
submitted
(132) Santillan, R.; Karlen, S.D.; Dang, H.; Garcia-Garibay, M. A., "Synthesis
and Characterization of Natural Abundance and Isotopically Labeled
1,4-Bis(3,3,3-triphenylpropynyl)-2,3-difluorobenzene. A Molecular Gyroscope with
a Polar Rotator" J. Mex. Chem. Soc., 2008, in press.
(131) Gould, S. L., Tranchemontagne, D., Yaghi, O. M., Garcia-Garibay,
M. A., "The Amphidynamic Character of Crystalline MOF-5: Rotational
Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered
Environment" J. Am. Chem. Soc., 2008,
130, manuscript published on the web February 21, 2008..
(130) Kuzmanich, G.; Natarajan, A,; Chin, K. K.; Veerman, M.; Mortko, C. J.;
Garcia-Garibay, M. A. "Solid State Photodecarbonylation of Diphenylcyclopropenone:
A Singlet State Quantum Chain Reaction Made Possible by Ultrafast Energy Transfer"
J. Am. Chem. Soc., 2008, 130, 1140-1141. (Highlighted in: Nature
2008, 451, 897)
(129) Chin, K. K., Chuang, S.-C.; Hernandez, B.; Campos, L. M.; Selke,
M.; Foote, C. S., Garcia-Garibay, M. A., "Photophysical Properties of
non-Homoconjugated 1, 2-dihydro, 1,2,3,4-tetrahydro and
1,2,3,4,5,6-hexahydro-C60 Derivatives" Photochem. Photobiol. Sci.
49-55.
(128) Resendiz, M. J. E., Natarajan, A., Garcia-Garibay, M. A.
"Diastereoselective Synthesis and Spin Dependent Photodecarbonylation of
di(3-phenyl-2-pyrrolidinon-3-yl) ketones: Synthesis of Nonadjacent and
Adjacent Stereogenic Quaternary Stereocenters" Chem Commun. 2007,
193-195.
(127) Resendiz, M. J. E., Taing, J., Khan, S. I., Garcia-Garibay, M.
A., "Unexpected Solid State Photochemistry of an a-
Thiophenyl-a'-Thiophenyl-S,S-dioxo Subsitituted Ketone," J. Org. Chem.
2008, 73, 638-643.
(126) Resendiz, M. J. E., Taing, J., Garcia-Garibay, M. A.,
"Photodecarbonylation of 1,3-Dithiophenyl Propanone: Using Nanocrystals to
Overcome the Filtering Effect of Highly Absorbing Trace Impurities"
Org. Letters 2007, 9, 4351-4354.

(125) Garica-Garibay, Miguel A. "Molecular Crystals on the Move: From
Single Crystal-to-Single Crystal Photoreactions to Molecular Machinery"
Angew Chem. Int. Ed. 2007, 8945-8947.
(124)
Grassian, V. H., Meyer, G., Abruna, H., Coates, G. W., Achenie, L. E,
Allison, T., Brunschwig, B., Ferry, J., Garcia-Garibay, M.,
Gardea-Torresdey, J., Grey, C. P., Hutchison, J., Li, C. J., Liotta, C.,
Ragauskas, A., Minteer, S., Mueller, K., Roberts, J., Sadik, O., Schmel,
R., Schneider, W., Selloni, A., Stair, P., Stewart, J., Thorn, D., Tyson,
J., Voelker, B., White, J. M., Wood-Black, F., "Chemistry for a
Sustainable Environment"
Environmental Science and Technology, 2007, 41,
3559-3561.
(123) Nunez, Jose E.; Natarajan, Arunkumar; Khan, Saeed I.;
Garcia-Garibay, Miguel A. "Synthesis of a Triply Bridged Molecular
Gyroscope by a Directed Meridional Cyclization Strategy" Organic
Lett.
2007, 9, 3559-3561.
(122) Natarajan, A.; Tsai, C. K.; Khan, S. I.; McCarren, P.; Houk, K.
N.; Garcia-Garibay, Miguel A. "The Photoarrangement of a-Santonin is a
Single-Crystal-to-Single-Crystal Reaction: A Long Kept Secret in Solid
State Organic Chemistry Revealed" J. Am. Chem. Soc. 2007, 129,
9846-9847.
(121) Natarajan, A.; Ng, D.; Yang, Z.; Garcia-Garibay, M. A., A Green
Chemistry Method for the Synthesis of Compounds with Adjacent Quaternary
Stereogenic Centers: Parallel Syntheses of (+) and (-)-a-Cuparenone by
Radical Combination in Crystalline Solids" Angew Chem. Int. Ed.
2007, 46,
6485-6487.
(120)
Chin, K. K.; Natarajan, A.; Campos, L. M.; Johansen, E.; Shepherd, H.;
Garcia-Garibay, M. A.; "Organic Molecular Nanocrystals: Triplet-Triplet
Absorption. Phosphorescence, and Circular Dichroism of Chiral Crystals of
Benzophenone" Chem. Commun. 2007, 41, 4266-4268.

(119)
Jarowski, P. D.; Houk, K. N.; Garcia-Garibay, M. A. "The
Importance of Correlated Motions on the Low Barrier Rotational Potentials
of Crystalline Molecular Gyroscopes" J. Am. Chem. Soc. 2007, 129,
3110-3117.

(118)
Campos, L. M.; Garcia-Garibay, M. A.; "Reactive Intermediates in
Crystals: Form and Function" in Reactive Intermediates, Platz, M. S.;
Jones, M.; Moss, R. Eds., Hoboken, NJ, 2007.
(117) Khuong, T. -A. V.; Dang, H.; Jarowski, P. D.; Maverick, E.;
Garcia-Garibay, M. A.; Rotational Dynamics of Crystalline Molecular
Gyroscope by Variable Temperature 13C NMR, 2H NMR, X-ray Diffraction and
Force Field Calculations," J. Am. Chem. Soc. 2007, 129, 839-845.
>
2006
(116) Chin, K. K., Chuang, S. C., Hernandez, B., Selke, M., Foote, C.
S., Garcia-Garibay, M. A., Photophysical Properties of a 1,2,3,4,5,6
Hexasubstituted Fullerene Derivative" J. Phys. Chem. 2006, 110,
13662-13666.
(115) Campos, L. M.; Mortko, C. J.; Garcia-Garibay, M. A.; "Norrish
Type I vs. Norrish-Yang Type II in the Solid State Photochemistry of
cis-2,6-Di(1-cyclohexenyl)-cyclohexanone: A computational study" Mol.
Cryst. Liq. Cryst. 2006, 456, 15-24.
(114) Karlen, S. D.; Khan, S. I.; Garcia-Garibay, M. A.; "Crystalline
Molecular Gyroscopes: The Effects of Subtle Molecular Differences on the
Crystal Packing of Triphenylmethyl and Triphenylsilyl Stators" Mol.
Cryst.
Liq. Cryst., 2006, 456, 221-230.
(113) Hornasky, R. D.; Clarke, L. I.; Winston, E. B.; Price, J. C.;
Karlen, S. D.; Jarowski, P. D.; Santillan, R.; Garcia-Garibay, M. A.;
"Observation of Dipolar Rotor-Rotor Interactions in Fluorobenzene
Molecular Rotor Crystals" Phys. Rev. B., 2006, 74, 054306.
(112) Karlen, S. D., Godinez, C., E., Garcia-Garibay, M., "Improved
Physical Properties and Rotational Dynamics in a Molecular Gyroscope with
an Assymmetric Stator Structure" Org Lett, 2006, 8, 2615-2617.
(111) Veerman, M., Resendiz, M. J. E., Garcia-Garibay, M. A.,
"Large-Scale Photochemical Reactions of Nanocrystalline Suspensions: A
Promising Green Chemistry Method" Org. Lett. 2006, 8, 2615-2617.
(110)
Khuong, T.-A. V., Nuñez, J. E., Godinez, C. E.,Garcia-Garibay,
M. A., "Crystalline Molecular Machines: A Quest Towards
Solid State Dynamics and Function." Acc. Chem. Res., 2006, 39,
413-422.
(109) Radhakrishnan, C.; Lo, M. K. F.; Garcia-Garibay, M.A.;
Monbouquette, H. G. .Photocatalytic Reduction of Azide Self Assembled
Monolayer using CdS Quantum Dots. Langmuir 2006, 22, 5018-5024.
(108) Choe, T.; Saeed I. Khan, S.I.; Garcia-Garibay, M.A. "
Combination Vs Disproportionation in Dialkyl Biradicals. Selectivity
Reversal in a Crystalline Solid" Photochem. Photobiol. Sc. 2006,
5, 449-451.
(107) Nuñez, J. E.; Khuong, T.-A.V.; Campos, L. M.; Farfan, N.; Dang,
H.; Karlen, S. D.; Garcia-Garibay, M.A." Crystal Phases and Phase
Transitions in a Highly Polymorphogenic Molecular Gyroscope with
meta-Methoxytrityl Frames " Cryst. Growth & Design, 2006, 6,
866-873.
(106) Mortko, C. J.; Garcia-Garibay, M. A. "Stereospecific Synthesis
of Compounds with Adjacent Chiral Quaternary Centers in Solid-to-Solid
Reactions" Topics in Stereochemistry, 2006, 25, 205-253.
(105) Karlen, Steven D.; Garcia-Garibay, Miguel A. "Amphidynamic
Crystals: Structureal Blueprints for Molecular Machines." Topics Curr.
Chem. 2006, 262, 179-228.
access pdf file
2005
(104) Garcia-Garibay, Miguel A. .Crystalline molecular machines:
Encoding supramolecular dynamics into molecular structure. Proc. Natl.
Acad. of Sci. 2005, 102, 10793(invited perspective article).
access pdf file
(103) Deniz Cizmeciyan, Ph.D.; Heather Yonutas; Steven D Karlen;
Miguel A. Garcia-Garibay, "2H NMR and X-ray diffraction studies of methyl
rotation in crystals of o-methyldibenzocycloalkanones" Solid State Mag.
Res., 2005, 28, 1-8.
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(102) Campos, Luis M.; Warrier, Manoj V.; Peterfy, Krisztina; Houk, K.
N.; Garcia-Garibay, Miguel A. .Secondary Alpha Isotope Effects on
Deuterium Tunneling in Triplet o-Methylanthrones: Extraordinary
Sensitivity to Barrier Width. J. Am. Chem. Soc. 2005, 127, 10178-10179.
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(101) Horansky, R. D.; Clarke, L. I.; Price, J. C.; Khuong, T.-A.V.;
Jarowski, P D.; Garcia-Garibay, M.A. "Dielectric Response of a Dipolar
Molecular Rotor Crystal" Phys. Rev. B., 2005, B72, 014302.
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(100) Mortko, C. J.; Garcia-Garibay, Miguel A., "Green Chemistry
Strategies Using Crystal-to-Crystal Photoreactions: Stereoselective
Synthesis and Decarbonylation of trans-...'-Dialkenoylcyclohexanones" J.
Am. Chem. Soc. 2005, 127, 7994-7995.
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(99) Karlen S. D.; Ortiz, R; Chapman, O. L.; Garcia-Garibay, M. A.
"Effects
of Rotational Order on the Solid State Dynamics of Phenylene and
Diamantane Rotators"
J. Am. Chem. Soc., 2005, 127, 6554 . 6555.
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(98) Resendiz, M.; Garcia-Garibay, Miguel A. "Hammet Substituent
Analysis on the
Photodecarbonylation of Crystalline 1,3-Diphenylacetones", Org. Letters,
2005, 7,
371-374.
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(97) Karlen, S. D: Garcia-Garibay, M.A., "Uncovering Hidden Gyroscopic
Motion in
Crystals by 13C CPMAS NMR with Isotopic Substitution and Selective Cross
Polarization"
Chem. Commun., 2005, 189-191.
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(96) Karlen, S. D: Kahn, S. I.; Garcia-Garibay, M.A. "Removal of
Conflicting Molecular
Symmetries Restores a Hexagonal Array of Six-Fold Phenyl Embraces in a
bis(Trityl)-Containing Compound. Part I. Crystals of
1,1,1,6,6,6-hexaphenyl-2,4-hexadiyne" Cryst. Growth & Design, 2005, 5,
53-55.
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2004
(95) Khuong, T.A.V.; Sanrame, C.N.; Zepeda, G.; Dang, H.; Bartberger,
M.; Houk, K.N.;
Garcia-Garibay, M.A. "Internal dynamics of a Highly Congested
Bis(triarylmethyl)peroxide:
Volume-Conserving Motions in a Simple Molecular Crankshaft." J. Am. Chem.
Soc., 2004, 126,
14778-14786
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(94) Warrier, Manoj; Lo, Michael K.F.; Monbouquette, Harold;
Garcia-Garibay, Miguel A.
"Photocatalytic Reduction of Aromatic Azides to Amines using CdS and CdSe
Nanoparticles"
Photochem. Photobiol. Sci., 2004, 3, 859-863.
(93) Carlos E. Godinez, Gerardo Zepeda, Christopher J. Mortko, Hung
Dang, and
Miguel A. Garcia-Garibay, "Molecular Crystals with Moving Parts:
Synthesis,
Characterization, and Crystal Packing of Molecular Gyroscopes with
Methyl-Substituted Triptycyl Frames" J. Org. Chem. 2004, 69,
1652-1662.
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(92) Ng, D.; Yang, Z.; Garcia-Garibay. M. A., "Total Synthesis of
(±)-Herbertenolide by Stereospecific Formation of Vicinal Quaternary
Centers
in a Crystalline Ketone" Org. Letters, 2004, 6, 645-647.
(91) Khuong, T.A.V.; Zepeda, G.; Ruiz, R.: Kahn, S. I.; Garcia-Garibay,
M.A.
"Molecular Compasses and Gyroscopes. Engineering Molecular Crystals with
Internal Rotation in the Gigaherz Regime" Cryst. Growth & Design, 2004, 4,
15-18.
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(91) Khuong, T.A.V.; Zepeda, G.; Ruiz, R.: Kahn, S. I.; Garcia-Garibay,
M.A.
"Molecular Compasses and Gyroscopes. Engineering Molecular Crystals with
Internal Rotation in the Gigaherz Regime" Cryst. Growth & Design, 2004, 4,
15-18.
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2003
(90) Ellison, M. E.; Ng, D.; Dang, H.; Garcia-Garibay, M.A.
“Enantiospecific
Synthesis of Vicinal Stereogenic Tertiary and Quaternary Centers by
Combination
of Configurationally-Trapped Radical Pairs in Crystalline Solids”
Organic
Letters, 2003, 5, 2531-2534.
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(89) Mortko, C. J.; Dang, D.; Campos. L. M. Garcia-Garibay, M. A.,
“H-Abstraction
prevails over a-cleavage in the solution and solid state photochemistry
of cis-2,6-di(1-cyclohexenyl)cyclohexanone”
Tetrahedron Lett. 2003, 44, 6133-6136.
access pdf file
(88) Dominguez, Z.; Khuong, T.A.V.; Sanrame, Dang, H.; Garcia-Garibay,
M. A.
“Molecular Compasses and Gyroscopes with Polar Rotors: Synthesis
and Characterization
of Crystalline Forms” J. Am. Chem. Soc., 2003 125, 8827-8837.
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(87) Garcia-Garibay, M.A., “Engineering” Carbene
Rearrangements
in Crystals: From Molecular Information to Solid State Reactivity”
Acc.
Chem. Res., 2003, 36, 491-498.
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(86) Garcia-Garibay, M.A.; Campos, L. “Photochemical
Decarbonylation
of Ketones: Recent Advances and Reactions in Crystalline Solids”
in The
Handbook for Organic Photochemistry and Photobiology, W. Horspool, Ed.,
CRC
Press, Boca Raton, Fl. 2003.
(85) Sanrame, C.N.; Suhrada, C. P.; Dang, H.; Garcia-Garibay, M. A.
“Photochemistry
of Crystalline Chlorodiazirines: The Influence of Conformational
Disorder and
Intermolecular Cl…N=N Interactions on the Solid State Reactivity
of Singlet
Chlorocarbenes” J. Phys. Chem. A 2003, 107, 3287-3294.
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(84) Amirsakis, D.G.; Elizarov, A. M.; Garcia-Garibay, M.A.; Glick, P.
T.;
Stoddart, J.F.; White, A. J. P.; Williams, D. J.
“Diastereospecific Photochemical
Dimerization of Stilbene-Containing Daisy Chain Monomers in Solution as
well
as in the Solid State” Angewandte Chemie, Int. Ed., 2003, 42,
1126-1132.
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2002
(83) Ng, D.; Yang, Z.; Garcia-Garibay, M.A. “Engineering
Reactions in
Crystals: Gem-dialkoxy Substitution Enables the Photodecarbonylation of
Crystalline
2-Indanone” Tetrahedron Lett. 2002, 43, 7063-7066.
(82) Johnson, B.; Kleinman, M.; Turro, N. J.; Garcia-Garibay, M.A.,
“Hydrogen
Atom Tunneling in Triplet ortho-Methylbenzocylanones: Effects of
Structure on
Reaction Geometry and Excited State Configuration.” J. Org. Chem.
2002,
67, 6944-6953.
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(81) Dominguez, Z.; Dang, H.; Strouse, J. M.; Garcia-Garibay, M. A.
“Molecular
“Compasses” and “Gyroscopes.” III. Two-Fold
Flipping
of a Phenylene Rotor and Six-Fold Rotation of Clathrated Benzene in a
Slipping-Gear
Crystal Lattice” J. Am. Chem. Soc., 2002, 105, 7719-7727.
(80) Campos, L. M.; Dang, H.; Ng, D.; Yang, Z.; Martinez, H. L.;
Garcia-Garibay,
M. A. “Engineering Reactions in Crystalline Solids: Predicting
Photochemical
Decarbonylation from Calculated Thermochemical Parameters” J. Org.
Chem.
2002, 67, 3749-3754.
access pdf file
(79) Godinez, C. E.; Zepeda, G.;Garcia-Garibay, M. A. “Molecular
Compasses
and Gyroscopes. II. Synthesis and Characterization of Molecular Rotors
with
Axially Substituted Bis-[2-(9-triptycyl)-ethynyl]arenes” J. Am.
Chem.
Soc. 2002, 105, 4701-4707.
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(78) Dominguez, Z.; Dang, H.; Strouse, M.J.; Garcia-Garibay, M.A.
“Molecular
Compasses and Gyroscopes I. Expedient Synthesis and Solid State Dynamics
of
an Open Rotor with a Bis(triarylmethyl) Frame. J. Am. Chem. Soc., 2002,
105,
2398-2399.
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(77) Schmieder, K.; Levitus, M.; Dang, H.; Garcia-Garibay, M.A.
“Photophysical
Properties of Coplanar and Twisted 1,4-Bis(9-ethynylanthracenyl)benzene.
Rotational
Equilibration in the Excited Sstates of Diaryalkynes.” J. Phys.
Chem.
A, 2002, 105, 1551-1556.
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2001
(76) Ng, D.; Yang, Z.; Garcia-Garibay, M.A.“Engineering reactions
in
crystals: supression of photodecarbonylation by intramolecular ?-phenyl
quenching”
Tetrahedron Lett., 2001, 42, 9113-9116.
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(75) Dang, H., Levitus, M., Garcia-Garibay, M.A., “One Step
Pd(0)-Catalyzed
Synthesis, X-Ray Analysis, and Photophysical Properties of
Cyclopent[hi]aceanthrylene:
Fullerene-Like Properties in a Non-alternant Cyclopenta-Fused Aromatic
Hydrocarbon”,
J. Am. Chem. Soc., 2002, 124, 136-143.
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(74) Amirsakis, D.G.; Garcia-Garibay, M.A.; Rowan, S.J.; Stoddart,
J.F.; White,
A. J. P.; Williams, D. J. “Host-Guest Chemistry Aids and Abets a
Stereospecific
Photodimerization in the Solid State.” Angew. Chem., 2001,
40, 4256-4261.
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(73) Johnson, B.; Houk, K.N., Garcia-Garibay, M.A.,
“Vibrationally Assisted
Tunneling in a Hydrogen Atom Transfer Reaction”, J. Am. Chem. Soc,
2001,
123, 6941-6942.
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(72) Yang, Z.; Ng, D.; Garcia-Garibay, M.A., “Engineering
Reactions in
Crystalline Solids: Photochemical Generation of Secondary and Tertiary
Enol
Radical Pairs from the Crystalline Ketodiesters.”, J. Org. Chem.,
2001,
66, 4468. access pdf file
(71) Garcia-Garibay, M.A. Review of Molecular and Supramolecular
Photochemistry,
Volume 5, Solid State and Surface Photochemistry by V. Ramamurthy and
Kirk S.
Schanze. Marcel Dekker: New York and Basel. 2000 J. Am. Chem. Soc.,
2001, 123,
5384-5384. BOOK REVIEW
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(70) Levitus, M.; Schmieder, K.; Ricks, H.; Schimizu, K.D.; Bunz,
U.H.F.; Garcia-Garibay,
M.A. “Steps to Demarcate the Effects of Chromophore Aggregation
and Planarization
in Poly(phenyleneethynylene)s. Part 1. Rotationally Interrupted
Conjugation
in the Excited States of 1,4-Bis(phenylethynyl)benzene”, J. Am.
Chem.
Soc,. 2001, 123, 4259-4265.
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(69) Levitus, M.; Zepeda, G.; Dang, H.; Godinez, C.; Khuong, T.-A. V.;
Schmieder,
K.; Garcia-Garibay, M.A.. “Steps to Demarcate the Effects of
Chromophore
Aggregation and Planarization in Poly(phenyleneethynylene)s Part 2. The
Photophysics
of 1,4-Diethynyl-2-fluorobenzene in Solution and in Crystals”, J.
Org.
Chem., 2001, 66, 3188-3195
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(68) Dang, H.; Garcia-Garibay, M.A., “Palladium-Catalyzed
Formation of
Aceanthrylenes: A Simple Method for Peri-Cyclopentenelation of Aromatic
Compounds.”
J. Am. Chem. Soc,. 2001, 123, 355-356.
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(67) Leyva, E.; Moctezuma, E.; Strouse, J.; Garcia-Garibay, M.A.
"Spectrometric
and 2D NMR Studies on the Complexation of Chlorophenols with
Cyclodextrins.''
J. Inclusion Phenomena, 2001, 39, 41-46.
2000
(66) Levitus, M.; Garcia-Garibay, M.A. “Polarized Electronic
Spectroscopy
and Photophysical Properties of 9,10-Bis(Phenylethynl)anthracene.”
J.
Phys. Chem. A, 2000, 104, 8632-8637.
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(65) Garcia-Garibay, M.A.; Shin, S.; Sanrame, C. "Engineering
Reactions
in Crystalline Solids: Prediction of Intramolecular Carbene
Rearrangements."
Tetrahedron, 2000, 56, 6729-6737.
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(64) Yang, Z.; Garcia-Garibay, M.A., "Engineering Reactions in
Crystalline
Solids: Preparation and Chemoselective Combination of ?-Carbonyl Radical
Pairs
in Crystals of Dialkyl-1,3-Acetonedicarboxylates." Organic Letters,
2000,
2,1963-1965.
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Earlier work
(63) Levitus, M.; Shick, G.; Lunkwitz, R.; Rubin, Y.; Garcia-Garibay,
M. A.
"Photophysical Properties of Hexapyrrolidine C60 Adducts with Th
and D3
Symmetry: Protonation of Multiple Basic Sites." J. Photochem.
Photobiol.
A. 1999, 127, 13-19.
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(62) Garcia-Garibay, M. A.; Houk, K. N.; Keating, A. E.; Cheer, C. J.;
Leibovitch,
M.; Scheffer, J. R.; Wu, L.-C. "Computational Modeling of an
Enantioselective
Solid State Photoreaction." Org. Letters, 1999, 8, 1279-1281.
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(61) Mendez F.; Garcia-Garibay, M.A. "A Hard-Soft Acid-Base and
DFT Analysis
of Singlet-Triplet Gaps and the Addition of Singlet Carbenes to
Alkenes."
J. Org. Chem., 1999, 64, 7061-7066.
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(60) Johnson, B. A.; Garcia-Garibay, M. A., "Rate Acceleration
below 20K
in the H-Atom Tunneling of Triplet ortho-Methyltetralones." J. Am.
Chem.
Soc., 1999, 121, 8114-8115.
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(59) Motschiedler, K. R.; Gudmsundsdottir, A.D.; Toscano, J.; Platz, M.
S.;
Garcia-Garibay, M. A.; "Excited Precursor Reactivity, Fast 1,2-H
Shifts
and Diffusion-Controlled Methanol Insertion in
1,2-Diphenylalkylidenes."
J. Org. Chem., 1999, 64, 5139-5147.
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(58) Schick, G.; Levitus, M.; Kvetko, L.; Johnson, B.A.; Lamparth, I.;
Lunkwitz,
R.; Ma, B.; Khan, S.; Garcia-Garibay, M.A.; Rubin, Y. "Unusual
Luminescence
of Hexapyrrolidine Derivatives of C60 with Th and Novel
D3-Symmetry." J.
Am. Chem. Soc., 1999, 121, 3246-3247.
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(57) Keating, A. E.; Shin, S.H.; Huang, F.; Garrell, R. L,;
Garcia-Garibay,
M. A.; "Experimental and Computational Modeling of Biphenyl
Twisting in
a Solid-to-Solid Carbene Reaction." Tetrahedron Lett., 1999,40,
261-264.
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(56) Garcia-Garibay, M. A., "Chemical Reactivity in Organized
Media."
Curr. Opinion in Solid State and Material Science, 1988, 3/4, 399-406
(invited
manuscript).
(55) Koshima, H.; Khan, S.I.; Garcia-Garibay, M. A. "Chiral
Crystalline
Salts from Achiral Biphenylcarboxylic Acids and Tryptamine."
Tetrahedron
Asymmetry, 1998, 9, 1851-1854..
(54) Keating, A. E.; Garcia-Garibay, M. A.; Houk, K. N. "Influence
of
Bystander Substituents on the Rates of 1,2-H and 1,2-Ph Shifts in
Singlet and
Triplet Carbenes." J. Phys. Chem.. 1998, 102, 8467-8476.
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(53) Johnson, B.A.; Garcia-Garibay, M. A., "Photochemistry Near
Zero Kelvin.
Quantum Mechanical Tunneling in the Photoenolization of
Ortho-Alkyl-Arylketones."
The Spectrum, 1998, 11, 1-7 (invited manuscript).
(52) Peterfy, K.; Garcia-Garibay, M. A. "Generation and Reactivity
of
a Triplet 1,4-Biradical Conformationally Trapped in a Crystalline
Cyclopentanone."
J. Am. Chem. Soc. 1998, 120, 4540-4541.
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(51) Gamarnik, A.; Johnson, B.A.; Garcia-Garibay, M. A., "Effects
of Solvents
on the Photoenolization of o-Methylanthrone at Low Temperatures.
Evidence for
H-Atom Tunneling from Nonequilibrating Triplets." J. Phys. Chem.
1998,
102, 5491-5498.
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(50) Keating, A. E.; Garcia-Garibay, M. A. "Photochemical
Solid-To-Solid
Reactions." in Organic and Inorganic Photochemistry, Ramamurthy, V.
and
Schanze, K., Eds..; Marcel Dekker: New York, 1998; Vol. 2; pp 195-248
(book
chapter).
(49) McAlpine, S. R.; Garcia-Garibay, M. A.; "Studies of Naphthyl
Substituted
?-Cyclodextrins. Self-Aggregation and Inclusion of External
Guests." J.
Am. Chem. Soc. 1998, 120, 4269-4275.
access pdf file
(48) Keating, A. E.; Garcia-Garibay, M. A.; Houk, K. N. "Origins
of Stereoselective
Carbene 1,2- Shifts and Cycloadditions of 1,2-Dichloroethylidene: A
Theoretical
Model Based on CBS-Q and B3LYP Calculations." J. Am. Chem. Soc.
1997, 119,
10805-10809.
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(47) Motschiedler, K. R.; Toscano, J.; Platz, M. S.; Garcia-Garibay, M.
A.
"Arylalkylcarbenes from Triplet Arylalkyldiazoalkanes."
Tetrahedron
Lett., 1997, 38, 949-952.
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(46) Shin, S.; Keating, A. E.; Cizmeciyan, D.; Khan, S. I.;
Garcia-Garibay,
M. A. "Control of Carbene Reactivity by Crystals. A Highly
Selectivity
1,2-H Shift in the Solid-to-Solid Reaction of
1-(4'-Biphenyl)-2-phenyl-diazopropane
to (Z)-1-(4'-Biphenyl)-2-phenyl-propene." J. Am. Chem. Soc., 1997,
119,
1859-1868.
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(45) Keating, A. E.; Shin, S.; Houk, K. N.; Garcia-Garibay, M. A.
" Combining
Quantum Mechanical Reaction Pathways with Force Field Lattice
Interactions to
Model a Solid State Phototransformation." J. Am. Chem. Soc. 1997,
119,
1474-1475.
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(44) Cizmeciyan, D.; Sonnichsen, L; Garcia-Garibay, M. A.
"Proximity,
Photochemical Reactivity, and Intermolecular 1H-13C Cross Polarization
in d10-Benzophenone
and Cyclohexane in the Zeolite NaX." J. Am. Chem. Soc. 1997, 119,
184-188.
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(43) Choi, T.; Peterfy, K.; Garcia-Garibay, M. A. "Molecular
Control of
Solid State Reactivity by Decarbonylation of Crystalline Ketones."
J. Am.
Chem. Soc., 1996, 118, 12477-12478.
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(42) McAlpine, S. R.; Garcia-Garibay, M. A. "Binding Studies of
Adamantane
Carboxylic Acid and a Naphthyl-Bound ?-Cyclodextrin by Variable
Temperature
1H NMR." J. Org. Chem., 1996, 61, 8307-8309.
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(41) Shin, S.; Constable, A.; Garcia-Garibay, M. A. "Transforming
a Non-Selective
Carbene Rearrangement into a Highly Selective Process by Using
Crystalline Media."
J. Am. Chem. Soc., 1996, 118, 7626-7627.
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(40) Garcia-Garibay, M. A.; Constable, A. E.; Jernelius, J. ; Choi, T.;
Cizmeciyan,
D.; Shin, S. H. "Diffraction Spectral and Thermal Analysis of Mixed
Crystalline
Phases. Mechanisms of Solid-to-Solid Organic Reactions." in
Physical Supramolecular
Chemistry, NATO ASI Series, Vol 485, 1996, pp. 289-312.
(39) McAlpine. S. R.; Garcia-Garibay, M. A. "Inside-Outside
Isomerism
of ß-Cyclodextrin Covalently Linked with a Naphthyl Group."
J. Am.
Chem. Soc., 1996, 118, 2750-2751.
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(38) Johnson, B. A.; Gamarnik, A.; Garcia-Garibay, M. A.
"Deuterium Tunneling
in Triplet 5,8-Dimethyl-1-tetralone by Phosphorescence Detection between
80
and 15K." Excellent Agreement between Phosphorescence and Flash
Photolysis
Data." J. Phys. Chem. 1996, 100, 4697-4700.
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(37) Garcia-Garibay, M. A.; Jenks, W. S.; Pang, L. "Heterogeneous
Hydrogen
and Deuterium Transfer in the Excited State of 2-Methylbenzophenone in
ether-pentane-alcohol
glasses at 77K." J. Photochem. Photobiol. A. 1996, 96, 51-55.
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(36) Ramamurthy, V; Garcia-Garibay, M. A. "Zeolites as
Supramolecular
Hosts for Photochemical Transformations." in Comprehensive
Supramolecular
Chemistry, G. Alberti and Bein, T., Eds., Elsevier, New York, 1996, Vol.
7,
Ch. 24., pp. 693-719.
(35) Choi, T.; Cizmeciyan, D.; Kahn, S. I.; Garcia-Garibay, M. A.
"An
Efficient Solid-to-Solid Reaction via a Steady-State Phase-Separation
Mechanism."
J. Am. Chem. Soc., 1995, 117, 12893-4.
(34) Garcia-Garibay, M. A.; A. Gamarnik; R. Bise; L. Pang; W. S. Jenks.
"Primary
Isotope Effects on Excited State Hydrogen Atom Transfer Reactions.
Activated
and Tunneling Mechanisms in an ortho-Methylanthrone." J. Am. Chem.
Soc.,
1995, 117, 10264-75.
(33) M. A. Garcia-Garibay, A. Gamarnik, L. Pang, W. S. Jenks.
"Excited
State Intramolecular Hydrogen Atom Transfer at Ultra-Low Temperatures.
Evidence
for Tunneling and Activated Mechanisms in 1,4-Dimethylanthrone", J.
Am.
Chem. Soc. 1994, 116, 12095-6
(32) Garcia-Garibay, M. A.; Shin, S. H.; Chao, I.; Houk, K. N.; Khan,
S. I.
"Solid State 13C CPMAS NMR and Molecular Mechanics Study of
Conformational
Recognition in Mixed Crystals of Two Phenylalkyl Ketones." Chem.
Mater.
1994, 6, 1297-1306
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(31) Evans, S. V.; Yee, V. C.; M., Garcia-Garibay; Trotter, J.
"Structure
of a Mixed Crystal of ?- and ?-Pipitzol (1:1), C15H20O3.C15H20O3."
Acta
Cryst. C., 1994 C50, 278-281.
(30) Winnik, F. M.; Ottaviani, M. F.; Bossmann, S. H.; Pan, W.;
Garcia-Garibay,
M. A.; Turro, N. J. "Phase Separation of
Poly-(N-Isopropylacrylamide) in
Water: A Spectroscopic Study of a Polymer Tagged with a Fluorescent Dye
and
a Spin Label." J. Phys. Chem. 1993, 97, 12998-13005.
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(29) Garcia-Garibay, M. A.; Theroff, C.; Shin, S. H.; Jernelius, J.
"Solvent
Effects on the Singlet-Triplet Equilibrium and Reactivity of A Ground
Triplet
State Arylalkyl Carbene." Tetrahedron Lett., 1993, 34 (2),
8415-18.
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(28) Ottaviani, M. F.; Garcia-Garibay, M. A.; Turro, N. J. "TEMPO
Radicals
as EPR Probes to Monitor the Adsorption of Different Species into
X-Zeolite."
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1993,
72,
321.
(27) Garcia-Garibay, M. A. "Reaction of Arylcarbenes with
Methanol. Triplet-State
Reactivity of Spin-State Equilibrium as a Moving Target?" J. Am.
Chem.
Soc., 1993, 115, 7011.
(26) Casswell, L.; Garcia-Garibay, M. A.; Scheffer, J. R.; Trotter, J.
"Optical
Activity Can Be Created from Nothing." J. Chem. Ed., 1993, 70,
785.
(25) Winnik, F. M.; Ottaviani, M. F.; Bossmann, S. H.; Pan, W.;
Garcia-Garibay,
M. A.; Turro, N. J. "Co-Non-Solvency of
Poly-(N-Isopropylacrylamide): A
Look at Spin-Labeled Polymers in Mixtures of Water and
Tetrahydrofuran."
Macromolecules, 1993, 26, 4577
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(24) Garcia-Garibay, M. A.; Ottaviani, M. F.; Turro, N. J. "Solid
State
NMR and EPR Studies of Intracrystalline vs. External Surface Adsorption
of Photoreactive
Ketones in Pentasil Zeolites." Mol. Crys. Liq. Crys. Inc. Nonlin.
Opt.,
1992, 211, 199.
(23) Garces, F. O.; Rao, V. P.; Garcia-Garibay, M. A.; Turro, N. J.
"A
Comparison of the 1H—13C Cross Polarization and Magic Angle
Spinning Dynamics
of the ??-,??-, and??-Cyclodextrin Inclusion Complexes of
Benzaldehyde."
J. Supramol. Chem., 1992, 1, 65.
(22) Winnik, F. M.; Ottaviani, M. F.; Bossmann, S. H.; Garcia-Garibay,
M. A.;
Turro, N. J. "Co-Non-Solvency of Poly-(N-Isopropylacrylamide) in
Mixed
Water-Methanol Solutions: A Look at Spin-Labeled Polymers."
Macromolecules,
1992, 25, 6007.
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(21) Garcia-Garibay, M. A.; Scheffer, J. R.; Watson, D.
"Prototropic Control
of Organic Photochemistry. Hydrogen Bonding Effects on the Di-pi-methane
Photorearrangement."
J. Org. Chem., 1992, 57, 241.
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(20) Garcia-Garibay, M. A.; Lei, X.; Turro, N. J. "Radical
Scavenging
in Zeolite Media." J. Am. Chem. Soc., 1992, 114, 2749.
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(19) Welsh, K. M.; Dektar, J. L.; Garcia-Garibay, M. A.; Hacker, N.;
Turro,
N. J. "Photo-CIDNP and Nanosecond Flash Photolysis Studies on the
Photodecomposition
of Triarylsulfonium Salts." J. Org. Chem., 1992, 57, 4179.
(18) Garcia-Garibay, M.; Zhang, Z.; Turro, N. J. "Diffusion and
Percolation
of Radical Pairs in Zeolite Media. A Product Analysis Study." J.
Am. Chem.
Soc., 1991, 113, 6212.
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(17) Ramamurthy, V.; Corbin, D. R.; Turro, N. J.; Zhang, Z.;
Garcia-Garibay,
M. "Modification of Photochemical Reactivity by Zeolites. A
comparison
between Zeolite-Solvent Slurry and Dry Solid State Photolyses." J.
Org.
Chem., 1991, 56, 255.
(16) Turro, N. J.; Garcia-Garibay, M. A. "Thinking Topologically
About
Photochemistry in Restricted Spaces." in Photochemistry in
Organized and
Constrained Media; Ramamurthy, V., Ed.; VCH Publishers, New York,
1991.
(15) Garcia-Garibay, M.; Scheffer, J. R.; Trotter, J.; Wireko, F.
"Crystal
Structures and Solid State Photochemistry of an Unsymmetrically
Substituted
Dibenzobarrelene and its Two Photoproducts
(Dibenzosemibullvalenes)." Acta
Cryst., 1990, B46, 79.
(14) Garcia-Garibay, M.; Scheffer, J. R.; Watson, D. "Prototropic
Control
of the Di-p-Methane Photorearrangement." J. Chem. Soc., Chem.
Comm., 1989,
600.
(13) Scheffer, J. R.; Garcia-Garibay, M. "Absolute Asymmetric
Synthesis
via Photochemical Reactions of Chiral Crystals." in Photochemistry
of Solid
Surfaces; Matsuura, T.; Anpo, M., Eds.; Elsevier, Amsterdam, 1989.
(12) Chen, J.; Garcia-Garibay, M.; Scheffer. "Chiral
Handle-Induced Diastereoselectivity
in an Organic Photorearrangement: Solution versus Solid State
Results."
Tetrahedron Lett., 1989, 30, 6125.
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(11) Ariel, S.; Garcia-Garibay, M. A.; Scheffer, J. R.; Trotter, J.
"Structure
of a Cyclization Photoproduct of
1-(4-Chlorophenyl)-2-Cyclohexanone." Acta
Cryst., 1989, C45, 1970.
(10) Ariel, S.; Garcia-Garibay, M.; Scheffer, J. R.; Trotter, J.
"Crystal
Structure of a Cyclization Photoproduct of
1-(4-Chlorophenyl)-2-Cyclooctylethanone,
and Reaction Pathway in Norrish Type II Cyclizations." Acta Cryst.,
1989,
B45, 153.
(9) Garcia-Garibay, M.; Scheffer, J. R.; Trotter, J.; Wireko, F.
"Determination
of the Absolute Steric Course of a Solid State Photorearrangement by
Anomalous
Dispersion X-Ray Crystallography." J. Am. Chem. Soc., 1989, 111,
4985.
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(8) Garcia-Garibay, M.; Scheffer, J. R.; Trotter, J.; Wireko, F.
"Intermolecular
Steric Effects on Unimolecular Rearrangements in Crystalline
Media." Tetrahedron
Lett., 1988, 29, 2041.
(7) Ariel, S.; Evans, S. V.; Garcia-Garibay, M.; Harkness, B. R.;
Omkaram,
N.; Scheffer, J. R.; Trotter, J. "The Generation of 1,4-Biradicals
in Rigid
Media: Crystal Structure-Solid State Reactivity Correlations." J.
Am. Chem.
Soc., 1988, 110, 5591.
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(6) Scheffer, J. R.; Trotter, J.; Garcia-Garibay, M.; Wireko, F.
"Studies
on the Di-p-Methane Rearrangement in the Solid State." Mol. Cryst.
Liq.
Cryst. Inc. Nonlin. Opt., 1988, 156, 63.
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(5) Garcia-Garibay, M.; Scheffer, J. R.; Trotter, J.; Wireko, F.
"Addition
of Bromine Gas to Crystalline Dibenzobarrelene: An Enantioselective
Carbocation
Rearrangement in the Solid State." Tetrahedron Lett., 1988, 29,
1485.
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(4) Garcia-Garibay, M.; Scheffer, J. R.; Trotter, J.; Wireko, J.
"Triplet
Energy Sensitization of a Crystalline Phase Photorearrangement."
Tetrahedron
Lett., 1987, 28, 1741.
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(3) Garcia-Garibay, M.; Scheffer, J. R.; Trotter, J.; Wireko, F.
"Generation
of Optical Activity Through Solid State Reaction of a Racemic Mixture
that Crystallizes
in a Chiral Space Group." Tetrahedron Lett., 1987, 28, 4789.
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(2) Evans, S. V.; Garcia-Garibay, M.; Omkaram, N.; Scheffer, J. R.;
Trotter,
J.; Wireko, F. "Use of Chiral Single Crystals to Convert Achiral
Reactants
to Chiral Products in High Optical Yield: Application to the
Di-p-Methane and
Norrish Type II Photorearrangements." J. Am. Chem. Soc., 1986, 108,
5648.
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(1) Scheffer, J. R.; Garcia-Garibay, M.; Omkaram, N. "The
Influence of
the Molecular Crystalline Environment on Organic
Photorearrangements."
in Organic Photochemistry; Padwa, A., Ed.; Marcel Dekker, New York,
1986, 249.
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