Publications
To request publications not posted here, please contact Professor Garcia-Garibay at
mgg@chem.ucla.edu.
2008 2007 2006 2005 2004 2003
2002 2001 2000 Pre-2000
2009
(147) Schlundt, S.; Kuzmanich, G.; Spanich, F.; Rojas, G. de M.; Kovacs, C.; Garcia-Garibay, M.A.; Guldi, D.M.;
Hirsch, A.
"Dendritic Porphyrin-Fullerene
Conjugates: Efficient Light-Harvesting and Charge-Transfer Events."Chem. Eur. Journal 2009,
VIP article
published on the Web Oct. 30, 2009.
(146) Simoncelli, S.; Kuzmanich, G.; Gard, M.N.; Garcia-Garibay, M.A. "Photochemical Reaction Mechanisms and Kinetics with Molecular Nanocrystals: Surface Quenching of Triplet Benzophenone
Nanocrystals." J. Phys. Org. Chem. 2009, manuscript accepted for publication.
(145) Rodriguez-Molina, B.; Ochoa, M.E.; Farfan, N.; Santillan, R.; Garcia-Garibay, M.A. "Synthesis, Characterization and Rotational
Dynamics of Crystalline Molecular Compasses With N-Heterocyclic Rotators." J. Org. Chem., published on the Web Oct. 22, 2009.
(144) Kuzmanich, G.; Gard, M.N.; Garcia-Garibay, M.A. "Photonic Amplification by a Singlet-State Quantum Chain Photodecarbonylation
Reaction in Crystalline Diarylcyclopropenones." J. Am. Chem. Soc. 2009, 131, 11606-11614.
(143) Hoijemberg, P.A.; Karlen, S.D.; Sanramé, C.N.; Aramendia, P.F.; Garcia-Garibay, M.A.
"Photolysis of an Asymmetrically Substituted Diazene in
Solution
and in the Crystalline State." Photochem. Photobiol. Sc. 2009, 8, 961-969.
(142) Godinez, C.E.; Garcia-Garibay, M.A.
"Engineering Crystal Packing and Internal Dynamics in Molecular Gyroscopes by Refining Their Components. Fast
Exchange of a Phenylene Rotator by 2H NMR." Cryst. Growth & Design 2009, 9, 3124-3128.
(141) Shiraki, S.; Garcia-Garibay, M.A. "Carbon-Carbon Bond Formation By Photoelimination of Small Molecules in Solution and in Crystals" in Handbook of
Synthetic Photochemistry, Albini, A., Ed., John Wiley, book chapter to be published in 2009.
(140) Mitsumori, T.; Campos, L.M.; Garcia-Garibay, M.A.; Wudl, F.; Sato, H.; Sato, Y. "Synthesis, Properties, and LED
Performance of Highly
Luminescent Metal Complexes Containing Indolizino[3,4,5-ab]isoindoles." J. Mat. Chem. 2009, 19, 5826-5836.
(139) Resendiz, M.J.E.; Family, F.; Fuller, K.; Campos, L.M.; Khan, S.I.; Lebedeva, N.V.; Forbes, M.D.E.; Garcia-Garibay, M.A.
"Radical Reactions with
Double Memory of
Chirality (2MOC) for the
Enantiospecific Synthesis of Adjacent Stereogenic Quaternary Centers in Solution: Cleavage and Bonding Faster than Radical Rotation."
J. Am. Chem.
Soc. 2009, 131, 8425-8433.
(138) Amboya, A.; Nguyen, T.; Huynh, H.T.; Brown, H.; Ratliff, G.; Yonutas, H.; Cizmeciyan, D.; Natarajan, A.; Garcia-Garibay, M.A.
"Radical Pairs with
Rotational Fluidity in the Photochemical Reaction of Acetophenone and Cyclohexane in the Zeolite NaY: A 13C CPMAS NMR and Product Analysis Study."
Org.
Biomol. Chem. 2009, 7, 2322-2326.
(137) Family, F.; Garcia-Garibay, M.A. "Photodecarbonylation of Ketodiacids as Ammonium Salts:
Efficient Formation of C-C Bonds Between Adjacent Quaternary
Centers in the Crystalline State." J. Org. Chem. 2009, 74, 2476-2480.
(136) Garcia-Garibay, M.A.; Dang, H.D. "Photochemical Generation, Intramolecular
Reactions, and Spectroscopic Detection of Oxonium Ylide and Carbene
Intermediates in a Crystalline ortho-(1,3-Dioxolan-2-yl)-diaryldiazomethane." Org. Biomol. Chem.
2009, 1106-1114.
2008 (back to top)
(135) Garcia-Garibay, M.A.
"Molecular Machines: Nanoscale Gadgets." Nature Materials 2008, 7, 431-432.
(134) Gould, S.L.; Rodriguez, R.B.; Garcia-Garibay, M.A. "Synthesis and Solid State Dynamics of Molecular Dirotors." Tetrahedron
2008, 64, 8336-8345.
(133) Chin, K.K.; Trevithick-Sutton, C.C.; McCallum, J.; Jockusch, S.; Turro,
N.J.; Scaiano, J.C.; Foote, C.S.; Garcia-Garibay, M.A.
"Quantitative Determination
of Singlet Oxygen Generated by Excited State Aromatic Amino Acids, Proteins, and
Immunoglobulins." J. Am. Chem. Soc. 2008, 130, 6912-6913.
(132) Santillan, R.; Karlen, S.D.; Dang, H.; Garcia-Garibay, M.A.
"Synthesis
and Characterization of Natural Abundance and Isotopically Labeled
1,4-Bis(3,3,3-triphenylpropynyl)-2,3-difluorobenzene. A Molecular Gyroscope with
a Polar Rotator." J. Mex. Chem. Soc. 2008, 52, 125-129.
(131) Gould, S.L.; Tranchemontagne, D.; Yaghi, O.M.; Garcia-Garibay,
M.A.
"Amphidynamic
Character of Crystalline MOF-5: Rotational
Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered
Environment." J. Am. Chem. Soc. 2008,
130, 3246-3247.
(130) Kuzmanich, G.; Natarajan, A.; Chin, K.K.; Veerman, M.; Mortko, C.J.;
Garcia-Garibay, M.A.
"Solid-State
Photodecarbonylation of Diphenylcyclopropenone:
A Quantum Chain Process Made Possible by Ultrafast Energy Transfer."
J. Am. Chem. Soc. 2008, 130, 1140-1141. (Highlighted in Nature
2008, 451, 897.)
(129) Chin, K.K.; Chuang, S.-C.; Hernandez, B.; Campos, L.M.; Selke,
M.; Foote, C.S., Garcia-Garibay, M.A.
"Photophysical Properties of
Non-Homoconjugated 1, 2-dihydro, 1,2,3,4-tetrahydro and
1,2,3,4,5,6-hexahydro-C60 Derivatives." Photochem. Photobiol. Sci. 2008,
1, 49-55.
(128) Resendiz, M.J.E.; Natarajan, A.; Garcia-Garibay, M.A.
"Diastereoselective Synthesis and Spin-Dependent Photodecarbonylation of
di(3-phenyl-2-pyrrolidinon-3-yl)Ketones: Synthesis of Nonadjacent and
Adjacent Stereogenic Quaternary Centers." Chem Commun.
2008,
193-195.
(127) Resendiz, M.J.E.; Taing, J.; Khan, S.I.; Garcia-Garibay, M.A.
"Unexpected
Solid-State Photochemistry of an &alpha-Thiophenyl-&alpha'-Thiophenyl-S,S-dioxo-Subsitituted Ketone."
J. Org. Chem.
2008, 73, 638-643.
2007 (back to top)
(126) Resendiz, M.J.E.; Taing, J.; Garcia-Garibay, M.A.
"Photodecarbonylation of 1,3-Dithiophenyl Propanone: Using Nanocrystals to
Overcome the Filtering Effect of Highly Absorbing Trace Impurities."
Org. Lett. 2007, 9, 4351-4354.
(125) Garcia-Garibay, M.A.
"Molecular Crystals on the Move: From
Single-Crystal-to-Single-Crystal Photoreactions to Molecular Machinery."
Angew Chem. Int. Ed. 2007, 46, 8945-8947.
(124) Grassian, V.H.; Meyer, G.; Abruna, H.; Coates, G.W.; Achenie, L.E.;
Allison, T.; Brunschwig, B.; Ferry, J.; Garcia-Garibay, M.A.;
Gardea-Torresdey, J.; Grey, C.P.; Hutchison, J.; Li, C.J.; Liotta, C.;
Ragauskas, A.; Minteer, S.; Mueller, K.; Roberts, J.; Sadik, O.; Schmel,
R.; Schneider, W.; Selloni, A.; Stair, P.; Stewart, J.; Thorn, D.; Tyson,
J.; Voelker, B.; White, J.M.; Wood-Black, F.
"Chemistry for a
Sustainable Future." Environ. Sci. Technol. 2007, 41,
3559-3561.
(123) Nunez, J.E.; Natarajan, A.; Khan, S.I.;
Garcia-Garibay, M.A.
"Synthesis of a Triply Bridged Molecular
Gyroscope by a Directed Meridional Cyclization Strategy." Org.
Lett.
2007, 9, 3559-3561.
(122) Natarajan, A.; Tsai, C.K.; Khan, S.I.; McCarren, P.; Houk, K.N.; Garcia-Garibay, M.A.
"The Photoarrangement of &alpha-Santonin
is a
Single-Crystal-to-Single-Crystal Reaction: A Long Kept Secret in Solid-State Organic Chemistry Revealed." J. Am. Chem.
Soc. 2007, 129,
9846-9847.
(121) Natarajan, A.; Ng, D.; Yang, Z.; Garcia-Garibay, M.A. "A Green
Chemistry Method for the Synthesis of Compounds with Adjacent Quaternary
Stereogenic Centers: Parallel Syntheses of (+) and (-)-a-Cuparenone by
Radical Combination in Crystalline Solids." Angew Chem. Int. Ed.
2007, 46,
6485-6487.
(120)
Chin, K.K.; Natarajan, A.; Gard, M.N.; Campos, L.M.; Johansson, E.; Shepherd, H.;
Garcia-Garibay, M.A.
"Pump-Probe Spectroscopy and Circular Dichroism of Nanocrystalline Benzophenone — Towards Absolute Kinetic Measurements in
Solid State Photochemical Reactions."
Chem. Commun. 2007, 41, 4266-4268.
(119) Jarowski, P.D.; Houk, K.N.; Garcia-Garibay, M.A.
"The
Importance of Correlated Motions on the Low Barrier Rotational Potentials
of Crystalline Molecular Gyroscopes." J. Am. Chem. Soc. 2007, 129,
3110-3117.
(118)
Campos, L.M.; Garcia-Garibay, M.A. "Reactive Intermediates in
Crystals: Form and Function" in Reactive Intermediates; Platz, M.S.,
Jones, M., Moss, R., Eds.; Hoboken, NJ, 2007.
(117) Khuong, T.-A.V.; Dang, H.; Jarowski, P.D.; Maverick, E.;
Garcia-Garibay, M.A.
"Rotational Dynamics in a Crystalline Molecular Gyroscope by Variable-Temperature 13C NMR, 2H NMR, X-Ray Diffraction, and
Force Field Calculations." J. Am. Chem. Soc. 2007, 129, 839-845.
2006 (back to top)
(116) Chin, K.K.; Chuang, S.C.; Hernandez, B.; Selke, M.; Foote, C.S.; Garcia-Garibay, M.A.
"Photophysical Properties of a 1,2,3,4,5,6-Hexasubstituted Fullerene Derivative." J. Phys. Chem. 2006, 110,
13662-13666.
(115) Campos, L.M.; Mortko, C.J.; Garcia-Garibay, M.A. "Norrish
Type I vs. Norrish-Yang Type II in the Solid State Photochemistry of
cis-2,6-Di(1-cyclohexenyl)-cyclohexanone: A computational study." Mol.
Cryst. Liq. Cryst. 2006, 456, 15-24.
(114) Karlen, S.D.; Khan, S.I.; Garcia-Garibay, M.A. "Crystalline
Molecular Gyroscopes: The Effects of Subtle Molecular Differences on the
Crystal Packing of Triphenylmethyl and Triphenylsilyl Stators." Mol.
Cryst. Liq. Cryst. 2006, 456, 221-230.
(113) Horansky, R.D.; Clarke, L.I.; Winston, E.B.; Price, J.C.;
Karlen, S.D.; Jarowski, P.D.; Santillan, R.; Garcia-Garibay, M.A. "Dipolar
Rotor-Rotor Interactions in a Difluorobenzene
Molecular Rotor Crystal." Phys. Rev. B 2006, 74, 054306.
(112) Karlen, S.D.; Godinez, C.E.; Garcia-Garibay, M.A. "Improved
Physical Properties and Rotational Dynamics in a Molecular Gyroscope with
an Assymmetric Stator Structure." Org. Lett. 2006, 8, 2615-2617.
(111) Veerman, M.; Resendiz, M.J.E.; Garcia-Garibay, M.A.
"Large-Scale Photochemical Reactions of
Nanocrystalline Suspensions: A
Promising Green Chemistry Method." Org. Lett. 2006, 8, 2615-2617.
(110) Khuong, T.-A.V.; Nuñez, J.E.; Godinez, C.E.; Garcia-Garibay, M.A.
"Crystalline Molecular Machines: A Quest Toward
Solid-State Dynamics and Function." Acc. Chem. Res. 2006, 39,
413-422.
(109) Radhakrishnan, C.; Lo, M.K.F.; Garcia-Garibay, M.A.; Warrier, M.V.; Monbouquette, H.G.
"Photocatalytic Reduction of an Azide-Terminated Self-Assembled
Monolayer Using CdS Quantum Dots." Langmuir 2006, 22, 5018-5024.
(108) Choe, T.; Khan, S.I.; Garcia-Garibay, M.A.
"Combination Vs. Disproportionation in Dialkyl Biradicals. Selectivity
Reversal in a Crystalline Solid." Photochem. Photobiol. Sci. 2006,
5, 449-451.
(107) Nuñez, J. E.; Khuong, T.-A.V.; Campos, L. M.; Farfan, N.; Dang,
H.; Karlen, S. D.; Garcia-Garibay, M.A.
"Crystal Phases and Phase
Transitions in a Highly Polymorphogenic Solid-State Molecular Gyroscope with
meta-Methoxytrityl Frames." Cryst. Growth & Design 2006, 6,
866-873.
(106) Mortko, C. J.; Garcia-Garibay, M.A. "Stereospecific Synthesis
of Compounds with Adjacent Chiral Quaternary Centers in Solid-to-Solid
Reactions." Topics in Stereochemistry 2006, 25, 205-253.
(105) Karlen, S.D.; Garcia-Garibay, M.A.
"Amphidynamic Crystals: Structureal Blueprints for Molecular Machines." Topics Curr.
Chem. 2006, 262, 179-228.
2005 (back to top)
(104) Garcia-Garibay, M.A. "Crystalline Molecular Machines:
Encoding Supramolecular Dynamics Into Molecular Structure." Proc. Natl.
Acad. of Sci. 2005, 102, 10793 (invited perspective article).
(103) Cizmeciyan, D.; Yonutas, H.; Karlen, S.D.; Garcia-Garibay, M.A.
"2H NMR and X-ray Diffraction Studies of Methyl
Rotation in Crystals of ortho-Methyldibenzocycloalkanones." Solid State Nuc. Mag.
Res. 2005, 28, 1-8.
(102) Campos, L.M.; Warrier, M.V.; Peterfy, K.; Houk, K.N.; Garcia-Garibay, M.A.
"Secondary Alpha Isotope Effects on
Deuterium Tunneling in Triplet o-Methylanthrones: Extraordinary Sensitivity to Barrier Width." J. Am. Chem. Soc. 2005, 127,
10178-10179.
(101) Horansky, R.D.; Clarke, L.I.; Price, J.C.; Khuong, T.-A.V.;
Jarowski, P.D.; Garcia-Garibay, M.A.
"Dielectric Response of a Dipolar
Molecular Rotor Crystal." Phys. Rev. B. 2005, B72, 014302.
(100) Mortko, C.J.; Garcia-Garibay, M.A.
"Green Chemistry
Strategies Using Crystal-to-Crystal Photoreactions: Stereoselective
Synthesis and Decarbonylation of trans-&alpha,&alpha'-Dialkenoylcyclohexanones." J.
Am. Chem. Soc. 2005, 127, 7994-7995.
(99) Karlen, S.D.; Ortiz, R.; Chapman, O.L.; Garcia-Garibay, M.A.
"Effects
of Rotational Order on the Solid State Dynamics of Phenylene and
Diamantane Rotators." J. Am. Chem. Soc. 2005, 127, 6554-6555.
(98) Resendiz, M.J.E.; Garcia-Garibay, M.A.
"Hammet Analysis of the
Photodecarbonylation in Crystalline 1,3-Diarylacetones." Org. Lett.
2005, 7,
371-374.
(97) Karlen, S.D.; Garcia-Garibay, M.A.
"Highlighting Gyroscopic
Motion in Crystals in 13C CPMAS Spectra by Specific Isotopic Substitution and Restricted Cross
Polarization." Chem. Commun. 2005, 189-191.
(96) Karlen, S.D.; Kahn, S.I.; Garcia-Garibay, M.A.
"Removal of
Conflicting Molecular
Symmetries Restores a Hexagonal Array of Six-Fold Phenyl Embraces in a
bis(Trityl)-Containing Compound. I. Crystals of
1,1,1,6,6,6-Hexaphenyl-2,4-hexadiyne." Cryst. Growth & Design 2005, 5,
53-55.
2004 (back to top)
(95) Khuong, T.A.V.; Sanrame, C.N.; Zepeda, G.; Dang, H.; Bartberger,
M.; Houk, K.N.; Garcia-Garibay, M.A.
"Crankshaft Motion in a Highly Congested Bis(triarylmethyl)peroxide." J. Am. Chem.
Soc. 2004, 126,
14778-14786.
(94) Warrier, M.; Lo, M.K.F.; Monbouquette, H.; Garcia-Garibay, M.A.
"Photocatalytic Reduction of Aromatic Azides to Amines using CdS and CdSe
Nanoparticles."
Photochem. Photobiol. Sci. 2004, 3, 859-863.
(93) Godinez, C.E.; Zepeda, G.; Mortko, C.J.; Dang, H.; Garcia-Garibay, M.A.
"Molecular Crystals with Moving Parts:
Synthesis, Characterization, and Crystal Packing of Molecular Gyroscopes with
Methyl-Substituted Triptycyl Frames." J. Org. Chem. 2004, 69,
1652-1662.
(92) Ng, D.; Yang, Z.; Garcia-Garibay. M.A.
"Total Synthesis of
(±)-Herbertenolide by Stereospecific Formation of Vicinal Quaternary
Centers
in a Crystalline Ketone." Org. Lett. 2004, 6, 645-647.
(91) Khuong, T.A.V.; Zepeda, G.; Ruiz, R.; Kahn, S.I.; Garcia-Garibay, M.A.
"Molecular Compasses and Gyroscopes: Engineering Molecular Crystals with
Fast Internal Rotation." Cryst. Growth & Design 2004, 4,
15-18.
2003 (back to top)
(90) Ellison, M.E.; Ng, D.; Dang, H.; Garcia-Garibay, M.A.
"Enantiospecific Synthesis of Vicinal Stereogenic Tertiary and Quaternary Centers by
Combination of Configurationally Trapped Radical Pairs in Crystalline Solids." Org.
Lett. 2003, 5, 2531-2534.
(89) Mortko, C.J.; Dang, D.; Campos. L.M.; Garcia-Garibay, M.A.
"H-Abstraction Prevails over &alpha-cleavage in the Solution and Solid State Photochemistry
of cis-2,6-di(1-cyclohexenyl)cyclohexanone." Tetrahedron Lett. 2003, 44, 6133-6136.
(88) Dominguez, Z.; Khuong, T.A.V.; Sanrame, C.N.; Dang, H.; Nuñez, J.E.; Garcia-Garibay, M.A.
"Molecular Compasses and Gyroscopes with Polar Rotors: Synthesis
and Characterization of Crystalline Forms." J. Am. Chem. Soc. 2003, 125, 8827-8837.
(87) Garcia-Garibay, M.A.
"Engineering Carbene
Rearrangements in Crystals: From Molecular Information to Solid-State Reactivity."
Acc. Chem. Res. 2003, 36, 491-498.
(86) Garcia-Garibay, M.A.; Campos, L.
"Photochemical Decarbonylation of Ketones: Recent Advances and Reactions in Crystalline Solids"
in The Handbook for Organic Photochemistry and Photobiology; Horspool, W., Ed.;
CRC Press: Boca Raton, FL, 2003.
(85) Sanrame, C.N.; Suhrada, C.P.; Dang, H.; Garcia-Garibay, M.A.
"Photochemistry of Crystalline Chlorodiazirines: The Influence of Conformational
Disorder and Intermolecular Cl...N=N Interactions on the Solid-State Reactivity
of Singlet Chlorocarbenes." J. Phys. Chem. A 2003, 107, 3287-3294.
(84) Amirsakis, D.G.; Elizarov, A.M.; Garcia-Garibay, M.A.; Glink, P.T.; Stoddart, J.F.; White, A.J.P.; Williams, D.J.
"Diastereospecific Photochemical Dimerization of a Stilbene-Containing Daisy Chain Monomer in Solution as
well as in the Solid State." Angewandte Chemie, Int. Ed. 2003, 42,
1126-1132.
2002 (back to top)
(83) Ng, D.; Yang, Z.; Garcia-Garibay, M.A.
"Engineering
Reactions in
Crystals: gem-Dialkoxy Substitution Enables the Photodecarbonylation of
Crystalline
2-Indanone." Tetrahedron Lett. 2002, 43, 7063-7066.
(82) Johnson, B.; Kleinman, M.H.; Turro, N.J.; Garcia-Garibay, M.A.
"Hydrogen
Atom Tunneling in Triplet o-Methylbenzocyloalkanones: Effects of
Structure on
Reaction Geometry and Excited State Configuration." J. Org. Chem.
2002,
67, 6944-6953.
(81) Dominguez, Z.; Dang, H.; Strouse, J.M.; Garcia-Garibay, M.A.
"Molecular 'Compasses' and 'Gyroscopes.' III. Dynamics of a Phenylene Rotor and Clathrated Benzene in a
Slipping-Gear
Crystal Lattice." J. Am. Chem. Soc. 2002, 124, 7719-7727.
(80) Campos, L.M.; Dang, H.; Ng, D.; Yang, Z.; Martinez, H.L.;
Garcia-Garibay, M. A.
"Engineering Reactions in Crystalline Solids: Predicting
Photochemical Decarbonylation from Calculated Thermochemical Parameters." J. Org.
Chem. 2002, 67, 3749-3754.
(79) Godinez, C.E.; Zepeda, G.; Garcia-Garibay, M.A.
"Molecular
Compasses
and Gyroscopes. II. Synthesis and Characterization of Molecular Rotors
with
Axially Substituted Bis[2-(9-triptycyl)ethynyl]arenes." J. Am.
Chem.
Soc. 2002, 124, 4701-4707.
(78) Dominguez, Z.; Dang, H.; Strouse, M.J.; Garcia-Garibay, M.A.
"Molecular
'Compasses' and 'Gyroscopes.' I. Expedient Synthesis and Solid State Dynamics
of an Open Rotor with a Bis(triarylmethyl) Frame." J. Am. Chem. Soc. 2002,
124, 2398-2399.
(77) Schmieder, K.; Levitus, M.; Dang, H.; Garcia-Garibay, M.A.
"Photophysical
Properties of Coplanar and Twisted 1,4-Bis(9-ethynylanthracenyl)benzene.
Rotational
Equilibration in the Excited States of Diaryalkynes." J. Phys.
Chem. A 2002, 105, 1551-1556.
(76) Dang, H.; Levitus, M.; Garcia-Garibay, M.A.
"One Step
Pd(0)-Catalyzed
Synthesis, X-Ray Analysis, and Photophysical Properties of
Cyclopent[hi]aceanthrylene:
Fullerene-Like Properties in a Nonalternant Cyclopentafused Aromatic
Hydrocarbon." J. Am. Chem. Soc. 2002, 124, 136-143.
2001 (back to top)
(75) Ng, D.; Yang, Z.; Garcia-Garibay, M.A.
"Engineering Reactions
in
Crystals: Supression of Photodecarbonylation by Intramolecular &beta-Phenyl
Quenching." Tetrahedron Lett. 2001, 42, 9113-9116.
(74) Amirsakis, D.G.; Garcia-Garibay, M.A.; Rowan, S.J.; Stoddart,
J.F.; White, A.J.P.; Williams, D.J.
"Host-Guest Chemistry Aids and Abets a
Stereospecific
Photodimerization in the Solid State." Angew. Chem. 2001,
40, 4256-4261.
(73) Johnson, B.A.; Houk, K.N.; Hu, Y.; Garcia-Garibay, M.A.
"Vibrationally Assisted
Tunneling in a Hydrogen Atom Transfer Reaction." J. Am. Chem. Soc.
2001,
123, 6941-6942.
(72) Yang, Z.; Ng, D.; Garcia-Garibay, M.A.
"Engineering
Reactions in
Crystalline Solids: Photochemical Generation of Secondary and Tertiary
Enol
Radical Pairs from the Crystalline Ketodiesters." J. Org. Chem.
2001,
66, 4468.
(71) Garcia-Garibay, M.A.
Book review of Solid State and Surface Photochemistry. Molecular and Supramolecular
Photochemistry,
Volume 5 by V. Ramamurthy and
Kirk S.
Schanze. Marcel Dekker: New York and Basel, 2000. J. Am. Chem. Soc.
2001, 123,
5384-5384.
(70) Levitus, M.; Schmieder, K.; Ricks, H.; Schimizu, K.D.; Bunz,
U.H.F.; Garcia-Garibay,
M.A.
"Steps to Demarcate the Effects of Chromophore Aggregation
and Planarization
in Poly(phenyleneethynylene)s. 1. Rotationally Interrupted
Conjugation
in the Excited States of 1,4-Bis(phenylethynyl)benzene." J. Am.
Chem.
Soc. 2001, 123, 4259-4265.
(69) Levitus, M.; Zepeda, G.; Dang, H.; Godinez, C.; Khuong, T.-A.V.;
Schmieder,
K.; Garcia-Garibay, M.A.
"Steps to Demarcate the Effects of
Chromophore
Aggregation and Planarization in Poly(phenyleneethynylene)s 2. The
Photophysics
of 1,4-Diethynyl-2-fluorobenzene in Solution and in Crystals." J.
Org.
Chem. 2001, 66, 3188-3195.
(68) Dang, H.; Garcia-Garibay, M.A.
"Palladium-Catalyzed
Formation of
Aceanthrylenes: A Simple Method for Peri-Cyclopentenelation of Aromatic
Compounds."
J. Am. Chem. Soc. 2001, 123, 355-356.
(67) Leyva, E.; Moctezuma, E.; Strouse, J.; Garcia-Garibay, M.A.
"Spectrometric
and 2D NMR Studies on the Complexation of Chlorophenols with
Cyclodextrins." J. Inclusion Phenomena 2001, 39, 41-46.
2000 (back to top)
(66) Levitus, M.; Garcia-Garibay, M.A.
"Polarized Electronic
Spectroscopy
and Photophysical Properties of 9,10-Bis(phenylethynl)anthracene."
J.
Phys. Chem. A 2000, 104, 8632-8637.
(65) Garcia-Garibay, M.A.; Shin, S.; Sanrame, C.
"Engineering
Reactions
in Crystalline Solids: Prediction of Intramolecular Carbene
Rearrangements." Tetrahedron 2000, 56, 6729-6737.
(64) Yang, Z.; Garcia-Garibay, M.A.
"Engineering Reactions in
Crystalline
Solids: Radical Pairs
in Crystals of Dialkyl 1,3-Acetonedicarboxylates." Org. Lett.
2000,
2, 1963-1965.
Earlier work (back to top)
(63) Levitus, M.; Shick, G.; Lunkwitz, R.; Rubin, Y.; Garcia-Garibay,
M. A.
"Photophysical Properties of Hexapyrrolidine C60 Adducts with Th
and D3
Symmetry: Protonation of Multiple Basic Sites." J. Photochem.
Photobiol. A. 1999, 127, 13-19.
(62) Garcia-Garibay, M.A.; Houk, K.N.; Keating, A.E.; Cheer, C.J.;
Leibovitch, M.; Scheffer, J.R.; Wu, L.-C.
"Computational Prediction of the
Enantioselectivity of a Solid-State Photoreaction." Org. Lett. 1999, 8, 1279-1281.
(61) Mendez, F.; Garcia-Garibay, M.A.
"A Hard-Soft Acid-Base and
DFT Analysis
of Singlet-Triplet Gaps and the Addition of Singlet Carbenes to
Alkenes." J. Org. Chem. 1999, 64, 7061-7066.
(60) Johnson, B.A.; Garcia-Garibay, M.A.
"Rate Acceleration
below 20K
in the H-Atom Tunneling of Triplet ortho-Methyltetralones." J. Am.
Chem.
Soc. 1999, 121, 8114-8115.
(59) Motschiedler, K.R.; Gudmsundsdottir, A.D.; Toscano, J.P.; Platz, M.;
Garcia-Garibay, M.A.
"Excited Precursor Reactivity, Fast 1,2-H
Shifts,
and Diffusion-Controlled Methanol Insertion in
1,2-Diphenylalkylidenes." J. Org. Chem. 1999, 64, 5139-5147.
(58) Schick, G.; Levitus, M.; Kvetko, L.; Johnson, B.A.; Lamparth, I.;
Lunkwitz, R.; Ma, B.; Khan, S.; Garcia-Garibay, M.A.; Rubin, Y.
"Unusual
Luminescence
of Hexapyrrolidine Derivatives of C60 with Th and Novel
D3-Symmetry." J. Am. Chem. Soc., 1999, 121, 3246-3247.
(57) Keating, A.E.; Shin, S.H.; Huang, F.; Garrell, R.L.;
Garcia-Garibay, M.A.
"Experimental and Computational Modeling of Biphenyl
Twisting in
a Solid-to-Solid Carbene Reaction." Tetrahedron Lett. 1999, 40,
261-264.
(56) Garcia-Garibay, M.A.
"Chemical Reactivity in Organized
Media: Statistical Entropy and Information in Crystals and Enzymes." Curr. Opinion in Solid State and Material Science
1988, 3/4, 399-406
(invited
manuscript).
(55) Koshima, H.; Khan, S.I.; Garcia-Garibay, M.A.
"Chiral
Crystalline
Salts from Achiral Biphenylcarboxylic Acids and Tryptamine."
Tetrahedron
Asymmetry 1998, 9, 1851-1854.
(54) Keating, A.E.; Garcia-Garibay, M.A.; Houk, K.N.
"Influence
of
Bystander Substituents on the Rates of 1,2-H and 1,2-Ph Shifts in
Singlet and
Triplet Carbenes." J. Phys. Chem. 1998, 102, 8467-8476.
(53) Johnson, B.A.; Garcia-Garibay, M.A.
"Photochemistry Near
Zero Kelvin.
Quantum Mechanical Tunneling in the Photoenolization of
Ortho-Alkyl-Arylketones." The Spectrum 1998, 11, 1-7 (invited manuscript).
(52) Peterfy, K.; Garcia-Garibay, M.A.
"Generation and Reactivity
of
a Triplet 1,4-Biradical Conformationally Trapped in a Crystalline
Cyclopentanone." J. Am. Chem. Soc. 1998, 120, 4540-4541.
(51) Gamarnik, A.; Johnson, B.A.; Garcia-Garibay, M.A.
"Effects
of Solvents
on the Photoenolization of o-Methylanthrone at Low Temperatures.
Evidence for
H-Atom Tunneling from Nonequilibrating Triplets." J. Phys. Chem. 1998,
102, 5491-5498.
(50) Keating, A.E.; Garcia-Garibay, M.A. "Photochemical
Solid-To-Solid
Reactions" in Organic and Inorganic Photochemistry; Ramamurthy, V., Schanze, K., Eds.; Marcel Dekker: New York,
1998, Vol. 2, pp. 195-248
(book
chapter).
(49) McAlpine, S.R.; Garcia-Garibay, M.A.
"Studies of Naphthyl-Substituted
&beta-Cyclodextrins. Self-Aggregation and Inclusion of External
Guests." J.
Am. Chem. Soc. 1998, 120, 4269-4275.
(48) Keating, A.E.; Garcia-Garibay, M.A.; Houk, K.N.
"Origins
of Stereoselective
Carbene 1,2-Shifts and Cycloadditions of 1,2-Dichloroethylidene: A
Theoretical
Model Based on CBS-Q and B3LYP Calculations." J. Am. Chem. Soc.
1997, 119,
10805-10809.
(47) Motschiedler, K.R.; Toscano, J.; Garcia-Garibay, M.A.
"Arylalkylcarbenes from Triplet Arylalkyldiazoalkanes."
Tetrahedron
Lett. 1997, 38, 949-952.
(46) Shin, S.; Keating, A.E.; Cizmeciyan, D.; Khan, S.I.;
Garcia-Garibay, M.A.
"Control of Carbene Reactivity by Crystals. A Highly
Selective
1,2-H Shift in the Solid-to-Solid Reaction of
1-(4'-Biphenyl)-2-phenyldiazopropane
to (Z)-1-(4'-Biphenylyl)-2-phenylpropene." J. Am. Chem. Soc. 1997,
119,
1859-1868.
(45) Keating, A.E.; Shin, S.H.; Houk, K.N.; Garcia-Garibay, M.A.
"Combining
Quantum Mechanical Reaction Pathways with Force Field Lattice
Interactions to
Model a Solid-State Phototransformation." J. Am. Chem. Soc. 1997,
119,
1474-1475.
(44) Cizmeciyan, D.; Sonnichsen, L.B.; Garcia-Garibay, M.A.
"Proximity,
Photochemical Reactivity, and Intermolecular 1H13C Cross Polarization
in d10-Benzophenone
and Cyclohexane in the Zeolite NaX." J. Am. Chem. Soc. 1997, 119,
184-188.
(43) Choi, T.; Peterfy, K.; Khan, S.I.; Garcia-Garibay, M.A.
"Molecular
Control of
Solid-State Reactivity and Biradical Formation from Crystalline Ketones."
J. Am.
Chem. Soc. 1996, 118, 12477-12478.
(42) McAlpine, S.R.; Garcia-Garibay, M.A.
"Binding Studies of
Adamantanecarboxylic Acid and a Naphthyl-Bound &beta-Cyclodextrin by Variable
Temperature
1H NMR." J. Org. Chem. 1996, 61, 8307-8309.
(41) Shin, S.H.; Keating, A.E.; Garcia-Garibay, M.A.
"Transforming
a Nonselective
Carbene Rearrangement into a Highly Selective Process by Using
Crystalline Media."J. Am. Chem. Soc. 1996, 118, 7626-7627.
(40) Garcia-Garibay, M.A.; Constable, A.E.; Jernelius, J.; Choi, T.;
Cizmeciyan, D.; Shin, S.H.
"Diffraction Spectral and Thermal Analysis of Mixed
Crystalline
Phases. Mechanisms of Solid-to-Solid Organic Reactions" in
Physical Supramolecular
Chemistry: NATO ASI Series 1996, 485, 289-312.
(39) McAlpine, S.R.; Garcia-Garibay, M.A.
"Inside-Outside
Isomerism
of &beta-Cyclodextrin Covalently Linked with a Naphthyl Group." J. Am.
Chem. Soc. 1996, 118, 2750-2751.
(38) Johnson, B.A.; Gamarnik, A.; Garcia-Garibay, M.A.
"Deuterium Tunneling
in Triplet 5,8-Dimethyl-1-tetralone by Phosphorescence Detection between
80
and 15K." J. Phys. Chem. 1996, 100, 4697-4700.
(37) Garcia-Garibay, M.A.; Jenks, W.S.; Pang, L.
"Heterogeneous
Hydrogen
and Deuterium Transfer in the Excited State of 2-Methylbenzophenone in
Ether-Pentane-Alcohol
Glasses at 77K." J. Photochem. Photobiol. A 1996, 96, 51-55.
(36) Ramamurthy, V; Garcia-Garibay, M.A.
"Zeolites as
Supramolecular
Hosts for Photochemical Transformations" in Comprehensive
Supramolecular
Chemistry; Alberti, G., Bein, T., Eds.; Elsevier: New York, 1996, Vol.
7,
Ch. 24, pp. 693-719.
(35) Choi, T.; Cizmeciyan, D.; Kahn, S.I.; Garcia-Garibay, M.A.
"An
Efficient Solid-to-Solid Reaction via a Steady-State Phase Separation
Mechanism." J. Am. Chem. Soc. 1995, 117, 12893-12894.
(34) Garcia-Garibay, M.A.; Gamarnik, A.; Bise, R.; Pang, L.; Jenks, W.S.
"Primary
Isotope Effects on Excited State Hydrogen Atom Transfer Reactions.
Activated
and Tunneling Mechanisms in an ortho-Methylanthrone." J. Am. Chem.
Soc. 1995, 117, 10264-10275.
(33) Garcia-Garibay, M.A.; Gamarnik, A.; Pang, L.; Jenks, W.S.
"Excited
State Intramolecular Hydrogen Atom Transfer at Ultralow Temperatures.
Evidence
for Tunneling and Activated Mechanisms in 1,4-Dimethylanthrone." J.
Am.
Chem. Soc. 1994, 116, 12095-12096.
(32) Garcia-Garibay, M.A.; Shin, S.H.; Chao, I.; Houk, K.N.; Khan,
S.I.
"Solid-State 13C CPMAS NMR and Molecular Mechanics Study of
Conformational
Recognition in Mixed Crystals of Two Phenylalkyl Ketones." Chem.
Mater. 1994, 6, 1297-1306.
(31) Evans, S.V.; Yee, V.C.; Garcia-Garibay, M.A.; Trotter, J.
"Structure
of a Mixed Crystal of &alpha- and &beta-Pipitzol (1:1), C15H20O3.C15H20O3."
Acta
Cryst. 1994, C50, 278-281.
(30) Winnik, F.M.; Ottaviani, M.F.; Bossmann, S.H.; Pan, W.;
Garcia-Garibay, M.A.; Turro, N.J.
"Phase Separation of
Poly-(N-isopropylacrylamide) in
Water: A Spectroscopic Study of a Polymer Tagged with a Fluorescent Dye
and
a Spin Label." J. Phys. Chem. 1993, 97, 12998-13005.
(29) Garcia-Garibay, M.A.; Theroff, C.; Shin, S.H.; Jernelius, J.
"Solvent
Effects on the Singlet-Triplet Equilibrium and Reactivity of a Ground
Triplet
State Arylalkyl Carbene." Tetrahedron Lett. 1993, 34 (2),
8415-8418.
(28) Ottaviani, M.F.; Garcia-Garibay, M.A.; Turro, N.J.
"TEMPO Radicals
as EPR Probes to Monitor the Adsorption of Different Species into
X-Zeolite."
Colloids and Surfaces A: Physicochemical and Engineering Aspects 1993,
72,
321.
(27) Garcia-Garibay, M.A.
"Reaction of Arylcarbenes with
Methanol: Triplet-State
Reactivity or Spin-State Equilibrium as a Moving Target?"
J. Am.
Chem.
Soc. 1993, 115, 7011.
(26) Casswell, L.; Garcia-Garibay, M.A.; Scheffer, J.R.; Trotter, J.
"Optical
Activity Can Be Created from Nothing."
J. Chem. Ed. 1993, 70,
785.
(25) Winnik, F.M.; Ottaviani, M.F.; Bossmann, S.H.; Pan, W.;
Garcia-Garibay, M.A.; Turro, N.J.
"Cononsolvency of
Poly(N-Isopropylacrylamide): A
Look at Spin-Labeled Polymers in Mixtures of Water and
Tetrahydrofuran."
Macromolecules 1993, 26, 4577.
(24) Garcia-Garibay, M.A.; Ottaviani, M.F.; Turro, N.J.
"Solid
State
NMR and EPR Studies of Intracrystalline vs. External Surface Adsorption
of Photoreactive
Ketones in Pentasil Zeolites." Mol. Crys. Liq. Crys. Inc. Nonlin.
Opt. 1992, 211, 199.
(23) Garces, F.O.; Rao, V.P.; Garcia-Garibay, M.A.; Turro, N.J.
"A
Comparison of the 1H—13C Cross Polarization and Magic Angle
Spinning Dynamics
of the &alpha-,&beta-, and &gamma-Cyclodextrin Inclusion Complexes of
Benzaldehyde."
J. Supramol. Chem. 1992, 1, 65.
(22) Winnik, F.M.; Ottaviani, M.F.; Bossmann, S.H.; Garcia-Garibay,
M.A.;
Turro, N.J.
"Cononsolvency of Poly(N-isopropylacrylamide) in
Mixed
Water-Methanol Solutions: A Look at Spin-Labeled Polymers."
Macromolecules 1992, 25, 6007-6017.
(21) Garcia-Garibay, M.A.; Scheffer, J.R.; Watson, D.G.
"Prototropic Control
of Organic Photochemistry. Hydrogen Bonding Effects on the Di-π-methane
Photorearrangement." J. Org. Chem. 1992, 57, 241.
(20) Garcia-Garibay, M.A.; Lei, X.; Turro, N.J.
"Radical
Scavenging
in Zeolite Media." J. Am. Chem. Soc. 1992, 114, 2749.
(19) Welsh, K.M.; Dektar, J.L.; Garcia-Garibay, M.A.; Hacker, N.P.;
Turro, N.J.
"Photo-CIDNP and Nanosecond Laser Flash Photolysis Studies on the
Photodecomposition
of Triarylsulfonium Salts." J. Org. Chem. 1992, 57, 4179-4184.
(18) Garcia-Garibay, M.A.; Zhang, Z.; Turro, N.J.
"Diffusion and
Percolation
of Radical Pairs in Zeolite Media. A Product Analysis Study."
J.
Am. Chem.
Soc. 1991, 113, 6212-6218.
(17) Ramamurthy, V.; Corbin, D.R.; Turro, N.J.; Zhang, Z.;
Garcia-Garibay, M.A.
"Modification of Photochemical Reactivity by Zeolites. A
Comparison
between Zeolite-Solvent Slurry and Dry Solid State Photolyses." J.
Org.
Chem. 1991, 56, 255-261.
(16) Turro, N.J.; Garcia-Garibay, M.A.
"Thinking Topologically
About
Photochemistry in Restricted Spaces" in Photochemistry in
Organized and
Constrained Media; Ramamurthy, V., Ed.; VCH Publishers: New York,
1991.
(15) Garcia-Garibay, M.; Scheffer, J.R.; Trotter, J.; Wireko, F.C.
"Crystal
Structures and Solid-State Photochemistry of an Unsymmetrically
Substituted
Dibenzobarrelene and Its Two Photoproducts
(Dibenzosemibullvalenes)." Acta Cryst. 1990, B46, 79-87.
(14) Garcia-Garibay, M.; Scheffer, J.R.; Watson, D.
"Prototropic
Control
of the Di-π-Methane Photorearrangement." J. Chem. Soc. Chem.
Comm. 1989, 600-601.
(13) Scheffer, J.R.; Garcia-Garibay, M.
"Absolute Asymmetric
Synthesis
via Photochemical Reactions of Chiral Crystals" in Photochemistry
of Solid
Surfaces; Matsuura, T., Anpo, M., Eds.; Elsevier: Amsterdam, 1989.
(12) Chen, J.; Garcia-Garibay, M.; Scheffer.
"Chiral
Handle-Induced Diastereoselectivity
in an Organic Photorearrangement: Solution Versus Solid State
Results." Tetrahedron Lett. 1989, 30, 6125.
(11) Ariel, S.; Garcia-Garibay, M.A.; Scheffer, J.R.; Trotter, J.
"Structure
of a Cyclization Photoproduct of
1-(4-Chlorophenyl)-2-Cyclohexylethanone." Acta
Cryst. 1989, C45, 1970-1973.
(10) Ariel, S.; Garcia-Garibay, M.; Scheffer, J.R.; Trotter, J.
"Crystal
Structure of a Cyclization Photoproduct of
1-(4-Chlorophenyl)-2-Cyclooctylethanone,
and Reaction Pathway in Norrish Type II Cyclizations." Acta Cryst.
1989,
B45, 153-158.
(9) Garcia-Garibay, M.; Scheffer, J.R.; Trotter, J.; Wireko, F.
"Determination
of the Absolute Steric Course of a Solid-State Photorearrangement by
Anomalous
Dispersion X-ray Crystallography." J. Am. Chem. Soc. 1989, 111,
4985.
(8) Garcia-Garibay, M.; Scheffer, J.R.; Trotter, J.; Wireko, F.
"Intermolecular
Steric Effects on Unimolecular Rearrangements in Crystalline
Media." Tetrahedron
Lett. 1988, 29, 2041.
(7) Ariel, S.; Evans, S.V.; Garcia-Garibay, M.; Harkness, B.R.;
Omkaram,
N.; Scheffer, J.R.; Trotter, J.
"The Generation of 1,4-Biradicals
in Rigid
Media: Crystal Structure-Solid State Reactivity Correlations." J.
Am. Chem.
Soc. 1988, 110, 5591.
(6) Scheffer, J.R.; Trotter, J.; Garcia-Garibay, M.; Wireko, F.
"Studies
on the Di-π-Methane Rearrangement in the Solid State." Mol. Cryst.
Liq.
Cryst. Inc. Nonlin. Opt. 1988, 156, 63.
(5) Garcia-Garibay, M.; Scheffer, J.R.; Trotter, J.; Wireko, F.
"Addition
of Bromine Gas to Crystalline Dibenzobarrelene: An Enantioselective
Carbocation
Rearrangement in the Solid State." Tetrahedron Lett. 1988, 29,
1485.
(4) Garcia-Garibay, M.; Scheffer, J. R.; Trotter, J.; Wireko, J.
"Triplet
Energy Sensitization of a Crystalline Phase Photorearrangement." Tetrahedron
Lett. 1987, 28, 1741.
(3) Garcia-Garibay, M.; Scheffer, J.R.; Trotter, J.; Wireko, F.
"Generation
of Optical Activity Through Solid State Reaction of a Racemic Mixture
that Crystallizes
in a Chiral Space Group." Tetrahedron Lett. 1987, 28, 4789.
(2) Evans, S.V.; Garcia-Garibay, M.; Omkaram, N.; Scheffer, J.R.;
Trotter,
J.; Wireko, F.
"Use of Chiral Single Crystals to Convert Achiral
Reactants
to Chiral Products in High Optical Yield: Application to the
Di-p-Methane and
Norrish Type II Photorearrangements." J. Am. Chem. Soc. 1986, 108,
5648.
(1) Scheffer, J.R.; Garcia-Garibay, M.; Omkaram, N. "The
Influence of
the Molecular Crystalline Environment on Organic
Photorearrangements" in Organic Photochemistry; Padwa, A., Ed.; Marcel Dekker: New York,
1986; p. 249.
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