Illustrated Glossary of Organic Chemistry
Mutarotation:
The change in optical rotation as a
monosaccharide
reaches equilibrium between its
α
and
β
anomers
.
α
-
D
-
glucopyranose
[α]
=
+
112.2
o
Equilibrium mixture
[α]
=
+
52.5
o
64%
β
and 36%
α
β
-
D
-
glucopyranose
[α]
=
+
18.7
o
Related terms:
Carbohydrate
,
pyranose,
optical activity
,
optically active
,
optically inactive
,
specific rotation
,
polarimetry
,
polarimeter
,
anomeric carbon
,
stereocenter
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