Illustrated Glossary of Organic Chemistry

Mutarotation: The change in optical rotation as a monosaccharide reaches equilibrium between its α and β anomers.






     




α-D-glucopyranose
[α] = +112.2o

Equilibrium mixture
[α] = +52.5o
64% β and 36% α

β-D-glucopyranose
[α] = +18.7o