Stereochemistry: Vocabulary

Exercise Solutions



Achiral: An object that is not chiral.


Chiral: An object that is not superposable with its mirror image.


Constitutional isomer: One of a set of isomers that differs in the sequence of attachment or bonding of the atoms.


Dextrorotatory: Rotation of plane polarized light in a clockwise direction.


Diastereomer: One of a set of stereoisomers that are not enantiomers.


Enantiomer: One of a pair of stereoisomers that are nonsuperposable mirror images.


Isomer: One of a set of compounds with identical molecular formulas.


Levorotatory: Rotation of plane polarized light in a counterclockwise direction.


Meso compound: A compound that has at least two stereocenters but is achiral.


Optically active: Rotation of plane polarized light.


Plane polarized light: Light in which the electric field component oscillates in a single plane.


Polarimeter: A device to measure rotation of plane polarized light.


Racemic mixture: An equimolar mixture of a pair of mutual enantiomers.


Resolution: Separation of mutual enantiomers.


Specific rotation: The magnitude of rotation of plane polarized light of compound in a 10.0 cm path length, and at concentration of 1.00g/mL or neat if the compound is a liquid.


Stereocenter: An atom that has four different groups attached to it.  (Not limited to just carbon.)


Stereoisomer: One of a set of isomers that have the same connectivity of atoms, but differ in the position of the atoms in space.  Stereoisomers cannot be interconverted by rotation around a single bond.  (Conformational isomers are not stereoisomers.)


Link to: Copyright 2000 by Steven A. Hardinger and Harcourt Brace & Company.  All rights reserved.