Critical Quench Comparison: phi0=0.76 T = 0.95 (A2 Runs)

Initially unstable with respect to PS only.

Comparing with A. Al Sunaidi's A2 run: phi0=0.76, T = 0.95, N=100.



Results based on the "old" and the "new" k1 (both defined on the introductory page) are shown below. Al Sunaidi's results reveal a t1/2 growth law, particularly for times of 20 < t < 40 (where tmax=40). This result does not appear to agree with our results for a similar quench with N=150. Where is the inconsistency?


A21-2-k2b_p-r1sc.pl4bsh.GIF


#1: Our results, "new" k1 -- from phi-based S(k):
Initially: R ~ t1/3.
t ~ 30: domain growth slows down.
Results disagree with Al Sunaidi's results which show R approaching a t1/2 growth law at late times. This inconsistency may arise from (1) our using a larger system size of N=150 or (2) our different definitions of k1. We use the "new" k1 definiton, whereas Al Sunaidi probably uses the "old" k1 one.
Plot #2 gives our results, assuming the "old" k1 definition. Plot #3 also uses the "old" k1, but examines the N=100 system.



A21-2-k2a-p-r1sc.pl2b2sh.GIF


#2: Our results, using "old" k1 -- from phi-based S(k).
Initially: R ~ t1/2.
t ~ 34: domain growth slows down.
Our early-time results appear to agree with Al Sunaidi's results of R ~ t1/2.



A2-kone2a-phi-r1sc.pl1dsh.GIF


#3: N=100 (like Al Sunaidi's system); using "old" k1 -- from phi-based S(k).
t~20 -> t~40: R~t1/2.
Our results appear to agree with Al Sunaidi's results. (Note: Al Sunaidi's results show tmax=40.)
Results based on "new" k1 values show that R~t1/3 up to t~40.

Further comments on this critical quench:
Resulting Morphology: Polymer-rich domains surrounded by disordered LC-rich regions. These polymer-rich domains coalesce and form stripes, as the LC-rich regions become more ordered and also form stripes. This stripe formation can be plausible since this is a critical quench and we expect a bicontinuous phase to form. A system size of N=100, however, may be too small for reliable results at late times. Al Sunaidi's results may still be reliable because these "stiff" stripes do not appear until times later than those he studied. Furthermore, as shown in the plots above, the t1/2 growth law can be obtained. His results, however, may not have sampled the truly late-time (but prior to when hydrodynamic effects matter) regime. Runs conducted on larger sizes under the same quenching conditions show no "stiff" stripes and thus imply that we need to examine a much larger system to study domain growth kinetics for this quench. (View N=100 phi and S profiles.)


Particular quenches:

phi0 T Suffix Run N # Configurations Comments
0.76 0.95 A2 100 1 "stiff" stripe phase
A21-2 150 1 Bicontinuous phase




Jump to the individual results of the quench with (phi0, T, N) of:

A2: 0.76, 0.95, 100 A21-2: 0.76, 0.95, 150 A4: 0.68, 0.95, 100 A4-1: 0.68, 0.95, 150 A41-250-2: 0.68, 0.95, 250
F31-2: 0.68, 0.75, 150 H21-2: 0.75, 0.75, 150 H41-2: 0.80, 0.75, 150 F61-2: 0.83, 0.75, 150 F21-2: 0.84, 0.75, 150
C2-1: 0.85, 0.75, 150 C21-250-2: 0.85, 0.75, 250 F5-2: 0.86, 0.75, 150 F11-2: 0.87, 0.75, 150 F4a-2: 0.88, 0.75, 150
E7-2: 0.89, 0.75, 150 E71-250-2: 0.89, 0.75, 250 G11-2: 0.68, 0.85, 150 H11-2: 0.75, 0.85, 150 H31-2: 0.80, 0.85, 150
G21-2: 0.83, 0.85, 150 G31-2: 0.84, 0.85, 150 G41-2: 0.85, 0.85, 150 G51-2: 0.86, 0.85, 150 G61-2: 0.87, 0.85, 150

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www.chem.ucla.edu/~aml/research.html

aml@chem.ucla.edu

Last updated August 1, 1999.