Comparing with A. Al Sunaidi's A2 run: phi0=0.76, T = 0.95, N=100.
Results based on the "old" and the "new" k1 (both defined on the introductory page) are shown below. Al Sunaidi's results reveal a t1/2 growth law, particularly for times of 20 < t < 40 (where tmax=40). This result does not appear to agree with our results for a similar quench with N=150. Where is the inconsistency?
#1: Our results, "new" k1 -- from phi-based S(k):
Initially: R ~ t1/3.
t ~ 30: domain growth slows down.
Results disagree with Al Sunaidi's results which show R approaching a t1/2 growth law at late times. This inconsistency may arise from (1) our using a larger system size of N=150 or (2) our different definitions of k1. We use the "new" k1 definiton, whereas Al Sunaidi probably uses the "old" k1 one.
Plot #2 gives our results, assuming the "old" k1 definition. Plot #3 also uses the "old" k1, but examines the N=100 system.
#2: Our results, using "old" k1 -- from phi-based S(k).
Initially: R ~ t1/2.
t ~ 34: domain growth slows down.
Our early-time results appear to agree with Al Sunaidi's results of R ~ t1/2.
#3: N=100 (like Al Sunaidi's system); using "old" k1 -- from phi-based S(k).
t~20 -> t~40: R~t1/2.
Our results appear to agree with Al Sunaidi's results. (Note: Al Sunaidi's results show tmax=40.)
Results based on "new" k1 values show that R~t1/3 up to t~40.
Further comments on this critical quench:
Resulting Morphology: Polymer-rich domains surrounded by disordered LC-rich regions. These polymer-rich domains coalesce and form stripes, as the LC-rich regions become more ordered and also form stripes. This stripe formation can be plausible since this is a critical quench and we expect a bicontinuous phase to form. A system size of N=100, however, may be too small for reliable results at late times. Al Sunaidi's results may still be reliable because these "stiff" stripes do not appear until times later than those he studied. Furthermore, as shown in the plots above, the t1/2 growth law can be obtained. His results, however, may not have sampled the truly late-time (but prior to when hydrodynamic effects matter) regime. Runs conducted on larger sizes under the same quenching conditions show no "stiff" stripes and thus imply that we need to examine a much larger system to study domain growth kinetics for this quench. (View N=100 phi and S profiles.)
| phi0 | T | Suffix Run | N | # Configurations | Comments |
|---|---|---|---|---|---|
| 0.76 | 0.95 | A2 | 100 | 1 | "stiff" stripe phase |
| A21-2 | 150 | 1 | Bicontinuous phase | ||
Jump to the individual results of the quench with (phi0, T, N) of:
Other links:
www.chem.ucla.edu/~aml/research.html
Last updated August 1, 1999.