Publications

2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996

pdf-version of complete publication list

2006 520 M. Frederick Hawthorne, Bhaskar M. Ramachandran, Robert D. Kennedy, Carolyn B. Knobler, “Approaches to Rotary Molecular Motors”, Proceedings of the Twelfth International Meeting on Boron Chemistry (IMEBORON XII), Pure Appl. Chem. (2006) (Submitted).
2005 519 Bradley W. Schuller. Peter J. Binns. Kent J. Riley, Ling Ma, Frederick Hawthorne, and Jeffrey A. Coderre, “ Selective Irradiation of the Vascular Endothelium Has No Effect on the Survival of Murine Intestinal Crypt Stem Cells”, Proc. Nat. Acad. Sci. (2005) (In press).
  518 Mark W. Lee, Omar Farha, Corwin Hansch, and M. Frederick Hawthorne, “Substituent Effects on the Electronic Properties of Ether Derivatives of Closo-B12(OH)12; Pseudo-metal Boron Cages with Tunable Redox Potentials”, J. Am. Chem. Soc.,(2005) (Submitted).
  517 Omar K. Farha, Richard L. Julius, M. Frederick Hawthorne, “Synthesis of a Homotrifunctional Conjugation Reagent Based on Maleimide Chemistry”, Tetrahedron Letters (2005) (Submitted)
  516 Tiejun Li, Julie Hamdi, and M. Frederick Hawthorne, “Unilamellar Liposomes with Enhanced Boron Content”, Bioconj. Chem. (2005) (In press).
515 Bhaskar M. Ramachandran and M. Frederick Hawthorne, "Synthesis and Structural Characterization of Symmetrical Closo-4,7-I 2-1,2-C2B10H10 and [(CH3)3NH][nido-2,4-I 2-7,8-C2B9H10]", Inorg. Chem., 45, 336-340 (2005).
  514 Tiejun Li, Satish S. Jalisatgi, Michael J. Bayer, Andreas Maderna, Saeed I. Khan, and M. Frederick Hawthorne, “Organic Syntheses on an Icosahedral Borane Surface: Closomer Structures with Twelvefold Functionality”, J. Am. Chem. Soc., 127, 17832-17841 (2005).
  513 Ling Ma, Julie Hamdi, Frances Wong, and M. Frederick Hawthorne, “Closomers of High Boron Content: Synthesis, Characterization, and Potential Application as Unimolecular Nanoparticle Delivery Vehicles for BNCT”, Inorg. Chem.,45, 278-285 (2005).
  512 Omar K. Farha, Richard L. Julius, Mark W. Lee, Ramon E. Huertas, Carolyn B. Knobler, and M. Frederick Hawthorne, “Synthesis of Stable Dodeca-(alkoxy) Derivatives of Hypercloso-B12H12”, J. Am. Chem. Soc., 127(51), 18243-18251 (2005).
  511 Bhaskar M. Ramachandran, Carolyn B. Knobler, and M. Frederick Hawthorne, “Example of an Intramolecular, Non-classical C-H--p Hydrogen Bonding Interaction in an Arylcarborane Derivative”, J. Mol. Struct. (2005).
  510 Ling Ma, Julie Hamdi, Jiaxing Huang, and M. Frederick Hawthorne, “Camouflaged Carborane Amphiphiles: Synthesis and Self-assembly”, Inorg. Chem., 44, 7249-7258 (2005).
  509 Hershel Jude, Hendrik Disteldorf, Sonja Fischer, Timothy J. Wedge, Adam M. Hawkridge, Atta M. Arif, M. Frederick Hawthorne, David C. Muddiman, and Peter J. Stang, “Coordination Driven Self-assemblies with a Carborane Backbone”, J. Am. Chem. Soc., 127, 12131-12139 (2005).
508

Axel Herzog, Satish S. Jalisatgi, Carolyn B. Knobler, Timothy J. Wedge, and M. Frederick Hawthorne, “Camouflaged Carborarods Derived from B-permethyl-1,12-diethynyl-para-and B-octamethyl-1,7-diethynyl-meta-carborane Modules”, Chem. Eur. J, 11, 7155-7174 (2005).

2004 507

Michael J. Bayer, Satish S. Jalisatgi, Brian Smart, Axel Herzog, Carolyn B. Knobler, and M. Frederick Hawthorne, “B-Octamethyl-[12]Mercuracarborand–4 as Host for “Naked” Fluoride Ions”, Angew. Chem. Int. Ed., 116, 1890-1893 (2004).

  506

D. Scott Wilbur, Ming-Kuan Chyan, Donald K. Hamlin, Brian B. Kegley, Ruedi Risler, Pradip M. Pathare, Janna Quinn, Robert L. Vessella, Catherine Foulon, Michael Zalutsky, Timothy J. Wedge, and M. Frederick Hawthorne, “Reagents for Astatination of Biomolecules. Comparison of the In Vivo Distribution and Stability of Some Radioiodinated and Astatinated Benzamidyl- and nido-Carboranyl Compounds”, Bioconj. Chem., 15, 203-223 (2004).

505

M. Frederick Hawthorne, Jeffrey I. Zink, Johnny M. Skelton, Michael J. Bayer, Chris Liu, Ester Livshits, Roi Baer, and Daniel Neuhauser, “Electrical or Photocontrol of the Rotary Motion of a Metallacarborane”, Science, 303, 1849-1851 (2004). [pdf]

 

504

Timothy J. Wedge, Axel Herzog, Ramón Huertas, Mark W. Lee, Carolyn B. Knobler and M. Frederick Hawthorne, “Metal-Metal Communication Through Carborane Cages Supporting Electroactive [h5-CpFe(CO)2] Substituents”, Organometallics, 23, 482 (2004).

 

503

Michael J. Bayer and M. Frederick Hawthorne, “An Improved Method for the Synthesis of [Closo-B12(OH)12]2-,” Inorg. Chem., 43, 2018-2020 (2004).

 2003

502

Tiejun Li, Jason Thomas, and M. Frederick Hawthorne, “Liposomes from Novel Carborane-containing Lipids for Boron Neutron Capture Therapy”, Abstract of papers, 225 th Annual ACS meeting, March 25, 2003. (2003).

 

501

Sean L. Johnston, Mark W. Lee, and M. Frederick Hawthorne, “Development of Cell-surface Protein Targeted CT and MR Contrast Agents”, Applied Radiology (Supplement), 70-77 (2003).

500

M. Frederick Hawthorne, “New Discoveries at the Interface of Boron and Carbon Chemistries,” Pure Appl. Chem., 75, 1157 (2003). [pdf]

 

499

M. Frederick Hawthorne, “Some Biomedical Applications of Aromatic Polyhedral Boranes and Their Progeny,” Special Publication of the King Faisal Foundation Honoring the King Faisal International Prize in Science 2003 (2003).

 

498

M. F Frederick Hawthorne, Satish Jalisatgi, Cynthia L. Beno, David E. Harwell and Carolyn B. Knobler, “Intra and Intermolecular Hydrogen Bonding in Some Cobaltacarboranes”, J. Mol. Struct., 656, 239-247 (2003).

 

497

M. Frederick Hawthorne and Mark W. Lee, “A Critical Assessment of Boron Target Compounds for Boron Neutron Capture Therapy”, J. Neuro-Oncol., 62, 33-45 (2003).

 

496

Yinghuai Zhu, Keith Carpenter, Ching Chi Bun, Stefan Bahnmueller, Chan Pek Ke, Venugopal    Shanmugham Srid, Leong Weng Kee, and M. Frederick Hawthorne, “(R)–Binap-Mediated Asymmetric Hydrogenation Using a Rhodacarborane Catalyst in Ionic Liquid Media,” Angew. Chem. Int. Ed. , 42, 3792 (2003).

 

495

Michael J. Bayer, Axel Herzog, Martin Diaz, George A. Harakas, Hans Lee, Carolyn B. Knobler, and M. Frederick Hawthorne, “The Synthesis of Carboracycles Derived from B,B`-Bis(aryl) Derivatives of Icosahedral ortho-Carborane,” Chem. Eur. J., 9, 2732 (2003). [pdf]

  494 Timothy J. Wedge and M. Frederick Hawthorne, “Multidentate Carborane-Containing Lewis Acids and Their Chemistry: Mercuracarborands,” Coord. Chem. Rev.  240, 111 (2003). [pdf]

2002

493

M. Frederick Hawthorne, “Further Advances at the Interface of Boron and Carbon Chemistries,” Proceedings of the Eleventh International Conference on Boron Chemistry, Published by the A. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Y. N. Bubanov, Editor., Moscow, Russia (2002).

 

492

Andreas Maderna Ramon Huertas, M. Frederick Hawthorne, Raymond Luguya, and M. Graca H. Vicente, “Synthesis of a Porphyrin-labeled Carboranyl Phosphate Diester: A Potential New Drug for Boron Neutron Capture Therapy,” Chem. Comm. 16, 1784 (2002).

 

491

M. Frederick Hawthorne, Kenneth Shelly, and Fangbiao Li, “Versatile Chemistry of the [B20H18]2- Ions: Novel Reactions and Structural Motifs,” Chem. Comm., 547 (2002).

2001

490

Mark B. Smuckler, Satish S. Jalisatgi, Lufeng Guan, Akira Nakanishi, Harumi Kasamatsu, and M. Frederick Hawthorne, “Boron-Rich Oligomeric Phosphate Diesters that Target the Cell Nucleus In Vitro,” Frontiers in Neutron Capture Therapy, Vol.2, M. Frederick Hawthorne, Kenneth Shelly and Richard J. Wiersema, Editors.  Kluwer Academic/Plenum Publishers: New York,  New York, 1103 (2001).

 

489

Fangbiao Li, Kenneth Shelly, Carolyn B. Knobler and M. Frederick Hawthorne, “Benzoquinone Oxidation of the [ae-B20H17NH3]3- and [ae-B20H17OH]4- Ions,” Frontiers in Neutron Capture Therapy, Vol.2, M. Frederick Hawthorne, Kenneth Shelly, and Richard J. Wiersema, Editors.  Kluwer Academic/Plenum Publishers: New York,  New York, 807 (2001).

 

488

Toralf Peymann, Kenneth Shelly and M. Frederick Hawthorne, “Recent Developments in the Chemistry of [B12H12]2-,” Frontiers in Neutron Capture Therapy, Vol.2, M. Frederick Hawthorne, Kenneth Shelly and Richard J. Wiersema, Editors.  Kluwer Academic/Plenum Publishers: New York, New York, 775 (2001).

  487

Toralf Peymann, Carolyn B. Knobler, Saeed I. Khan and M. Frederick Hawthorne, “Dodecahydroxy-closo-dodecaborate (2-),” J. Am. Chem. Soc. 123, 2182 (2001).

 

486

K.J. Stelzer, P. R. Gavin, R. Risler, H. Kippenes, M. F. Hawthorne, D.W. Nigg and G. E. Laramore, “Boron Neutron Capture-Enhanced Fast Neutron Therapy (BNC/FNT) for Non-Small Cell Lung Cancer in Canine Patients,” Frontiers in Neutron Capture Therapy, Vol.1, M. Frederick Hawthorne, Kenneth Shelly and Richard J. Wiersema, Editors.  Kluwer Academic/Plenum Publishers: New York, New York, 735 (2001).

 

485

Axel Herzog, Carolyn B. Knobler and M. Frederick Hawthorne,  “Synthesis, Structure and Reactivity of closo-2,3,4,5,6,7,8,9,10,11-decahydroxy-1,12-bis-(sulfonicacid)-1,12-dicarbadodecaborane (12),” J. Am. Chem. Soc. 123, 12791 (2001).

 

484

Andreas Maderna, Axel Herzog Carolyn B. Knobler and M. Frederick Hawthorne, “The Syntheses of Amphiphilic Camouflaged Carboranes as Modules for Supramolecular Construction,” J. Am. Chem. Soc. 123, 10423 (2001).

 

483

M. Frederick Hawthorne, “Obituary:  Donald J. Cram (1919-2001),” Nature 412, 696 (2001).

 

482

George E. Laramore, K.J. Stelzer, R. Risler, J.L. Schwartz, J.J. Douglas, J.P. Einck, D.W. Nigg, C.A. Wemple, J.K. Hartwell, Y.D. Harker, Patrick R. Gavin and M. Frederick Hawthorne,  “Neutron Capture Therapy (NCT) Enhancement of Fast Neutron Radiotherapy:  Application to Non-Small Cell Lung Cancer,” Proceedings of the Sixteenth International Conference on Application of Accelerators in Research and Industry, J.L. Duggan and I.L. Morgan, Editors. American Institute of Physics (2001).

 

481

Jason Thomas and M. Frederick Hawthorne, “Dodeca(carboranyl)-substituted Closomers: Toward Unimolecular Nanoparticles as Delivery Vehicles for BNCT,” Chem. Comm., 1884 (2001).

 

480

Theodore W. Bitner, Timothy J. Wedge, M. Frederick Hawthorne and Jeffrey I. Zink, “Synthesis and Luminescence Spetroscopy of a Series of [h5-CpFe(CO)2] Complexes Containing 1,12-Dicarba-closo-dodecaboranyl  and -ylene Ligands,” Inorg. Chem. 40, 5428 (2001).

 

479

Hans Lee, Carolyn B. Knobler and M. Frederick Hawthorne, “A Hydrogen Bonded [(Mercuracarborand-Water)2-Benzene]  p-Sandwich Complex,” Angew. Chem. Int. Ed. 40, 3058 (2001).

 

478

Hans Lee, Carolyn B. Knobler and M. Frederick Hawthorne, “Octahedral Coordination of Halide Ions (I-, Br-, Cl-) Sandwich Bonded with Tridentate Mercuracarborand-3 Receptors,” J. Am. Chem. Soc. 123, 8543 (2001).

 

477

Hans Lee, Carolyn B. Knobler and M. Frederick Hawthorne, “Modular Self-Assembly of A Microporous Solid Based upon Mercuracarborand-4 and A New Bonding Motif,” Angew. Chem. Int. Ed. 40, 2124 (2001).

 

476

Axel Herzog, Ryan P. Callahan, Charles L.B. Macdonald, Vincent M. Lynch, M. Frederick Hawthorne and Richard J. Lagow, “A Perfluorinated Nanosphere: Synthesis and Structure of Perfluoro-deca-B-methyl-para-carborane,” Angew. Chem. Int. Ed. 40, 2121 (2001).

 

475

Toralf Peymann, Carolyn Knobler, Saeed I. Khan and M. Frederick Hawthorne, “Dodeca(benzyloxy)dodecaborane,B12(OCH2Ph)12: A Stable Derivative of hypercloso-B12H12,” Angew. Chem. Int. Ed. 40, 1664 (2001). [pdf]

 

474

Andreas Maderna, Carolyn Knobler and M. Frederick Hawthorne, “Twelvefold Functionalization of an Icosahedral Surface by Total Esterification of [B12(OH)12]2-: 12(12)-Closomers,” Angew. Chem. Int. Ed. 40, 1661 (2001). [pdf]

 

473

Toralf Peymann, Carolyn B. Knobler, Saeed I. Khan and M. Frederick Hawthorne, “Dodecamethyl-closo-dodecaborate(2-),” Inorg. Chem. 40, 1291 (2001). [pdf]

2000

472

Hans Lee, Carolyn B. Knobler and M. Frederick Hawthorne, “Supramolecular Self-Assembly Directed by Carborane C-H¼F Interactions,” Chem. Comm. 24, 2485 (2000).

 

471

Ibrahim H.A. Badr, R. Daniel Johnson, Martin Diaz, M. Frederick Hawthorne and Leonidas G.      Bachas, “A Selective Optical Sensor Based on [9]Mercuracarborand-3, A New Type of Ionopore with a Chloride Complexing Cavity,” Anal. Chem., 72, 4249 (2000).

 

470

Juston J. Rockwell, Axel Herzog, Toralf Peymann, Carolyn B. Knobler and M. Frederick  Hawthorne, “Recent Advances in the Field of Camouflaged Carboranes and Polyhedral Boranes,” Current Sci., 78, 405 (2000).

 

469

Hans Lee, Martin Diaz, Carolyn Knobler and M. Frederick Hawthorne, “Octahedral Coordination of Iodide in an Electrophilic Sandwich,” Angew. Chem. Int. Ed., 39, 776 (2000).

 

468

Toralf Peymann, Carolyn B. Knobler and M. Frederick Hawthorne, “A Study of the Sequential Acid-Catalyzed Hydroxylation of Dodecahydro-closo-Dodecaborate(2-),” Inorg. Chem., 39, 1163 (2000).

 

467

M. Frederick Hawthorne, “Broadening the Conflux of Boron and Carbon Chemistries,”  Proceedings of the Tenth International Conference on Boron Chemistry, Contemporary Boron Chemistry, Edited by M. Davidson, A.K. Hughes, T.B. Marder and K. Wade, Royal Society of Chemistry:  Cambridge, 197 (2000).

 

466

Weilin Chen, Martin Diaz, Juston Rockwell, Carolyn B. Knobler and M. Frederick Hawthorne,   “Synthesis and Characterization of Water-Soluble Boron-Substituted Ortho-Carborane Derivatives,” Comptes Rendus de l’Académie des Sciences – Série IIcChemie, 3, 223 (2000).

1999

465

Akira Nakanishi, Lufeng Guan, Robert R. Kane, Harumi Kasamatsu and M. Frederick Hawthorne, “Toward a Cancer Therapy with Boron-rich Oligomeric Phosphate Diesters that Target the Cell Nucleus,” Proc. Natl. Acad. Sci. USA, 96, 238 (1999).

 

464

M. Frederick Hawthorne and Andreas Maderna, “Applications of Radiolabeled Boron Clusters to the Diagnosis and Treatment of Cancer,” Chem. Rev., 99, 3421 (1999).

 

463

Toralf Peymann, Carolyn B. Knobler, and M. Frederick Hawthorne, “An Unpaired Electron Incarcerated Within an Icosahedral Borane Cage:  Synthesis and Crystal Structure of the Blue, Air-Stable {[closo-B12(CH3)12].}- Radical,” Chem. Comm., 2039 (1999).

 

462

Fangbiao Li, Kenneth Shelly, Carolyn B. Knobler, and M. Frederick Hawthorne, “The Synthesis of [Me4N]2[a2-B20H16(NH3)2] and trans-B20H16(NH3)2 from [Me3NH][cis-B20H17NH3] and Their Structural Characterization,” Inorg. Chem., 38 , 4926 (1999).

 

461

Toralf Peymann, Carolyn B. Knobler, and M. Frederick Hawthorne, “An Icosahedral Array of Methyl Groups Supported by an Aromatic Borane Scaffold: The [closo-B12(CH3)12]2- Ion,” J. Am. Chem. Soc., 121, 5601 (1999).

 

460

Hans Lee, Martin Diaz and M. Frederick Hawthorne, “Mercuracarborand-Catalyzed Diels-Alder Reaction of a Thionoester with Cyclopentadiene,” Tetahedron Lett., 40, 7651 (1999).

 

459

David M. Schubert, David E. Harwell, Carolyn B. Knobler and M. Frederick Hawthorne, “Structural Characterization of Charge Transfer Complexes of the Nickel(IV) Bis-(3,1,2-Dicarbollyl) Sandwich Compound,” Acta Chemica Scandinavia, Festchrift , 53, 721 (1999).

 

458

Axel Herzog, Andreas Maderna, George N. Harakas, Carolyn B. Knobler and M. Frederick Hawthorne, “A Camouflaged Nido-Carborane Anion: Facile Synthesis of Octa-B-methyl-1,2-dicarba-closo-dodecaborane(12) and Its Deboration Reaction,” Chem. Eur. J., 5, 1212 (1999).

 

457

Ibrahim H. A. Badr, Martin Diaz, M. Frederick Hawthorne and Leonidas G. Bachas,  Mercuracarborand “Anti-Crown Ether” Based Chloride Sensitive Liquid/Polymeric Membrane Electrodes,” Anal. Chem., 71, 1371 (1999).

 

456

Alfred A. Zinn, Carolyn B. Knobler, David E. Harwell, and M. Frederick Hawthorne, “Molecular Aggregates of Nitrate Ion with the Tetravalent Lewis Acid Host 12-Mercuracarborand-4:  Novel Trihapto Coordination of NO3_,” Inorg. Chem., 38, 2227 (1999).